Dibenzoyl-L-tartaric acid
Dibenzoyl-L-tartaric acid Basic information
- Product Name:
- Dibenzoyl-L-tartaric acid
- Synonyms:
-
- (2R,3R)-(-)-DI-O-BENZOYL-TARTARIC ACID
- (2R,3R)-(-)-DIBENZOYL-L-TARTARIC ACID
- BUTANEDIOIC ACID, 2,3-BIS(BENZOYLOXY)-, (2R,3R)-
- di-1,4-o-benzoyl-l-tartaric acid
- DI-O-BENZOYL-L-TARTARIC ACID
- (-)-DIBENZOYL-L-TARTARIC ACID
- DIBENZOYL-L-TARTARIC ACID
- L-DI-O-BENZOYLTARTARIC ACID
- CAS:
- 2743-38-6
- MF:
- C18H14O8
- MW:
- 358.3
- EINECS:
- 220-374-0
- Product Categories:
-
- Chiral Compound
- chiral
- straight chain compounds
- Anilines, Amides & Amines
- Bromine Compounds
- Carboxylic Acids (Chiral)
- Pharmaceutical Intermediates
- FINE Chemical & INTERMEDIATES
- Chiral Compounds
- Chiral Building Blocks
- Synthetic Organic Chemistry
- CHIRAL CHEMICALS
- Hydroxy Acids & Deriv.
- Aromatics
- Chiral Reagents
- Miscellaneous Reagents
- 2743-38-6
- Mol File:
- 2743-38-6.mol
Dibenzoyl-L-tartaric acid Chemical Properties
- Melting point:
- 152-155 °C(lit.)
- Boiling point:
- 234 °C / 7mmHg
- Density
- 1.3806 (rough estimate)
- vapor pressure
- 0Pa at 20℃
- refractive index
- -116 ° (C=1, EtOH)
- storage temp.
- Refrigerator
- solubility
- DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
- pka
- 1.85±0.25(Predicted)
- form
- Solid or Crystalline Powder
- color
- Off-white to orange to pale brown
- optical activity
- [α]20/D 116°, c = 9 in ethanol
- Water Solubility
- Slightly soluble in water.
- BRN
- 709854
- InChIKey
- YONLFQNRGZXBBF-ZIAGYGMSSA-N
- LogP
- 1.01 at 20℃
- CAS DataBase Reference
- 2743-38-6(CAS DataBase Reference)
- EPA Substance Registry System
- Butanedioic acid, 2,3-bis(benzoyloxy)-, (2R,3R)- (2743-38-6)
MSDS
- Language:English Provider:L(-)-Dibenzoyl-L-tartaric acid
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Dibenzoyl-L-tartaric acid Usage And Synthesis
Description
Dibenzoyl-L-tartaric acid is a kind of white crystalline powder, and odorless, mildly bitter flavor, be slightly soluble in water, and pH value is 3-4, in acid, dissolves in ethanol and acetone and other organic solvent. Be widely used in chiral separation of racemic amine compounds. Because it is cheap, has stable properties, and is easy to recycle, it has good industrial application value.
Chemical Properties
Dibenzoyl-L-tartaric acid is white to light yellow crystal powde
Uses
(-)-Dibenzoyl-L-tartaric acid, anhydrous is used as a reagent used to produce chiral salts. Also used as organic chemical synthesis intermediate.
Flammability and Explosibility
Not classified
Safety Profile
Dibenzoyl-L-tartaric acid is an eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Synthesis
A synthetic method of Dibenzoyl-L-tartaric acid includes the following steps: with L-tartaric acid and benzoyl chloride as raw materials, copper sulfate as a catalyst and toluene as a solvent, carrying out reaction to prepare L-dibenzoyl tartaric anhydride, carrying out hydrolysis with an equal amount of water and toluene to obtain the L-dibenzoyl tartaric acid, wherein the toluene serving as the solvent, as well as the water and the toluene in the hydrolysis step, can be repeatedly utilized.
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Dibenzoyl-L-tartaric acid(2743-38-6)Related Product Information
- D(-)-Tartaric acid
- Benzoyl chloride
- Glycine
- Folic acid
- DL-Tartaric acid
- Benzoyl peroxide
- PHENYLGLYOXAL MONOHYDRATE
- Ethyl 2-(Chlorosulfonyl)acetate
- (+)-Dibenzoyl-D-tartaric acid
- L(+)-Tartaric acid
- Methyl benzoylformate
- Voriconazole
- (-)-Di-p-toluoyl-L-tartaric acid
- Dibenzoyltartaric acid
- 2,3-Di-O-para-toluoyl-D-tartaric acid
- (-)-Dibenzoyl-L-tartaric acid monohydrate
- Di-p-anisoyl-D-tartaric acid
- Di-p-anisoyl-L-tartaric acid