(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Basic information
- Product Name:
- (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
- Synonyms:
-
- Diaminocyclohexanediylbispyridinecarboxamide
- (1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane
- (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%
- (-)-N,N''-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%
- (R,R)-DACH-pyridyl Trost ligand
- 1R,2R- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide)
- 2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine
- (R,R)-DACH-pyridyl Trost ligand 95%
- CAS:
- 218290-24-5
- MF:
- C18H20N4O2
- MW:
- 324.38
- Product Categories:
-
- DACH&Trost Series
- Chiral Nitrogen
- Mol File:
- 218290-24-5.mol
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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Chemical Properties
- Melting point:
- 170°C
- alpha
- -95° (c 1, CH3OH)
- Boiling point:
- 663.4±50.0 °C(Predicted)
- Density
- 1.25±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- pka
- 12.51±0.40(Predicted)
- color
- off-white
- optical activity
- [α]20/D -97.0°, c = 1 in methanol
- InChI
- 1S/C18H20N4O2/c23-17(15-9-3-5-11-19-15)21-13-7-1-2-8-14(13)22-18(24)16-10-4-6-12-20-16/h3-6,9-14H,1-2,7-8H2,(H,21,23)(H,22,24)/t13-,14-/m1/s1
- InChIKey
- BVYFDUZVVBXFBQ-ZIAGYGMSSA-N
- SMILES
- O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccn2)c3ccccn3
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Safety Information
- Risk Statements
- 36/37/38-22
- Safety Statements
- 26-36/37/39-36/37
- WGK Germany
- 3
- Storage Class
- 11 - Combustible Solids
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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Usage And Synthesis
Reaction
- Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
- Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers.
Uses
(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)Supplier
J & K SCIENTIFIC LTD.
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006356688 18621169109
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Beijing HwrkChemical Technology Co., Ltd
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- 010-89508211 18501085097
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BeiJing Hwrk Chemicals Limted
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- 0757-86329057 18934348241
- sales4.gd@hwrkchemical.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)(218290-24-5)Related Product Information
- 1,2-CyclohexanediaMine, N,N,N'-triMethyl-, trans-
- (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
- 2-(CYCLOHEXYLAMINOMETHYL)PYRIDINE
- N,N'-BIS-2-PYRIDYLMETHYL ETHYLENEDIAMINE
- TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE
- Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine
- (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
- N,N'-Dimethyl-1,2-cyclohexanediamine