(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

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Product Name: (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
CAS No.: 218290-24-5
Chemical Name: (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
Synonyms: (R,R)-DACH-pyridyl Trost ligand;(R,R)-DACH-pyridyl Trost ligand 95%;Diaminocyclohexanediylbispyridinecarboxamide;2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine;(R,R)-DACH-pyridyl Trost ligand;trans-1,2-Bis(2-pyridinecarboxamido)cyclohexane;N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide;(1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane;N,N'-(1R,2R)-1,2-Cyclohexanediyldi(2-pyridinecarboxamide);rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide
CBNumber: CB3262425
Molecular Formula: C18H20N4O2
Formula Weight: 324.38
MOL File: 218290-24-5.mol

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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Property

Melting point:: 170°C
alpha: -95° (c 1, CH3OH)
Boiling point:: 663.4±50.0 °C(Predicted)
Density: 1.25±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
pka: 12.51±0.40(Predicted)
color: off-white
optical activity: [α]20/D -97.0°, c = 1 in methanol
InChI: 1S/C18H20N4O2/c23-17(15-9-3-5-11-19-15)21-13-7-1-2-8-14(13)22-18(24)16-10-4-6-12-20-16/h3-6,9-14H,1-2,7-8H2,(H,21,23)(H,22,24)/t13-,14-/m1/s1
InChIKey: BVYFDUZVVBXFBQ-ZIAGYGMSSA-N
SMILES: O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccn2)c3ccccn3

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Safety

Risk Statements: 36/37/38-22
Safety Statements: 26-36/37/39-36/37
WGK Germany: 3
Storage Class: 11 - Combustible Solids

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692751
Product name: (R,R)-DACH-pyridyl Trost ligand
Purity: 95%
Packaging: 500mg
Price: $115
Updated: 2023/06/20

Sigma-Aldrich

Product number: 692751
Product name: (R,R)-DACH-pyridyl Trost ligand
Purity: 95%
Packaging: 1g
Price: $173
Updated: 2023/06/20

Strem Chemicals

Product number: 07-0340
Product name: (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (R,R)-DACH-Pyridyl Trost Ligand
Packaging: 1g
Price: $108
Updated: 2024/03/01

Strem Chemicals

Product number: 07-0340
Product name: (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (R,R)-DACH-Pyridyl Trost Ligand
Packaging: 5g
Price: $427
Updated: 2024/03/01

ChemScene

Product number: CS-W009874
Product name: rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide]
Purity: >97.0%
Packaging: 1g
Price: $60
Updated: 2021/12/16

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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Chemical Properties,Usage,Production

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Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Preparation Products And Raw materials

Raw materials

Preparation Products

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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Suppliers

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View Lastest Price from (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (R,R)-DACH-pyridyl Trost ligand 218290-24-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

218290-24-5, (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)Related Search:

1,2-CyclohexanediaMine, N,N,N'-triMethyl-, trans- (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) 2-(CYCLOHEXYLAMINOMETHYL)PYRIDINE N,N'-BIS-2-PYRIDYLMETHYL ETHYLENEDIAMINE TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) N,N'-Dimethyl-1,2-cyclohexanediamine

Diaminocyclohexanediylbispyridinecarboxamide

(1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane

(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%

(-)-N,N''-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%

(R,R)-DACH-pyridyl Trost ligand

1R,2R- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide)

2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine

(R,R)-DACH-pyridyl Trost ligand 95%

(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%

(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE),MIN.98%(R,R)-DACH-PYRIDYLTROSTLIGAND

(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (R,R)-DACH-Pyridyl Trost Ligand

N-[(1R,2R)-2-(pyridine-2-carbonylamino)cyclohexyl]pyridine-2-carboxamide

rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide]

trans-1,2-Bis(2-pyridinecarboxamido)cyclohexane

(1R,2R)-N,N'-1,2-Diaminocyclohexanediylbis(2-pyridinec arboxamide),99%e.e.

2-Pyridinecarboxamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis-, rel-

N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide[(R,R)-DACH-pyridyl Trost ligand

(-)-N,N'-(1R,2R)-1,2-DiaMinocyclohexanediylbis(2-pyridinecarboxaMide)

N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide

rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide

(1R,2R)-N,N'-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide)

(<i>R</i>,<i>R</i>)-DACH-pyridyl Trost ligand

N,N'-(1R,2R)-1,2-Cyclohexanediyldi(2-pyridinecarboxamide)

218290-24-5

DACH&Trost Series

Chiral Nitrogen