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ChemicalBook > CAS DataBase List > (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

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Product Name
(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
CAS No.
218290-24-5
Chemical Name
(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
Synonyms
(R,R)-DACH-pyridyl Trost ligand;(R,R)-DACH-pyridyl Trost ligand 95%;Diaminocyclohexanediylbispyridinecarboxamide;2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine;trans-1,2-Bis(2-pyridinecarboxamido)cyclohexane;N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide;N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide;(1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane;rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide;rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide]
CBNumber
CB3262425
Molecular Formula
C18H20N4O2
Formula Weight
324.38
MOL File
218290-24-5.mol
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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Property

Melting point:
170°C
Boiling point:
663.4±50.0 °C(Predicted)
alpha 
-95° (c 1, CH3OH)
Density 
1.25±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
12.51±0.40(Predicted)
form 
Powder
color 
off-white
optical activity
[α]20/D -97.0°, c = 1 in methanol
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Safety

Risk Statements 
36/37/38-22
Safety Statements 
26-36/37/39-36/37
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692751
Product name
(R,R)-DACH-pyridyl Trost ligand
Purity
95%
Packaging
500mg
Price
$115
Updated
2023/06/20
Sigma-Aldrich
Product number
692751
Product name
(R,R)-DACH-pyridyl Trost ligand
Purity
95%
Packaging
1g
Price
$173
Updated
2023/06/20
Strem Chemicals
Product number
07-0340
Product name
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (R,R)-DACH-Pyridyl Trost Ligand
Packaging
1g
Price
$108
Updated
2024/03/01
Strem Chemicals
Product number
07-0340
Product name
(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (R,R)-DACH-Pyridyl Trost Ligand
Packaging
5g
Price
$427
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0004311
Product name
(-)-N,N'-(1R,2R)-1,2-DIAMINO CYCLOHEXANEDIYL BIS(2-PYRIDINE CARBOXAMIDE)
Purity
95.00%
Packaging
500MG
Price
$588.06
Updated
2021/12/16
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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Chemical Properties,Usage,Production

Reaction

  1. Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
  2. Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Preparation Products And Raw materials

Raw materials

Preparation Products

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(-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Suppliers

China 40 Germany 1 Japan 1 Norway 1 Switzerland 1 United States 5 Global 49
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View Lastest Price from (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(R,R)-DACH-pyridyl Trost ligand 218290-24-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

218290-24-5, (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)Related Search:

1,2-CyclohexanediaMine, N,N,N'-triMethyl-, trans- (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) 2-(CYCLOHEXYLAMINOMETHYL)PYRIDINE N,N'-BIS-2-PYRIDYLMETHYL ETHYLENEDIAMINE TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) N,N'-Dimethyl-1,2-cyclohexanediamine

  • (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
  • Diaminocyclohexanediylbispyridinecarboxamide
  • (1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane
  • (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%
  • (-)-N,N''-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%
  • (R,R)-DACH-pyridyl Trost ligand
  • 1R,2R- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide)
  • 2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine
  • (R,R)-DACH-pyridyl Trost ligand 95%
  • (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%
  • (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE),MIN.98%(R,R)-DACH-PYRIDYLTROSTLIGAND
  • (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (R,R)-DACH-Pyridyl Trost Ligand
  • N-[(1R,2R)-2-(pyridine-2-carbonylamino)cyclohexyl]pyridine-2-carboxamide
  • rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide]
  • trans-1,2-Bis(2-pyridinecarboxamido)cyclohexane
  • (1R,2R)-N,N'-1,2-Diaminocyclohexanediylbis(2-pyridinec arboxamide),99%e.e.
  • N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide
  • 2-Pyridinecarboxamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis-, rel-
  • (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
  • N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide[(R,R)-DACH-pyridyl Trost ligand
  • (-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98%
  • (-)-N,N'-(1R,2R)-1,2-DiaMinocyclohexanediylbis(2-pyridinecarboxaMide)
  • N,N'-(trans-Cyclohexane-1,2-diyl)dipicolinamide
  • rel-N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-pyridinecarboxamide
  • 218290-24-5
  • DACH&Trost Series
  • Chiral Nitrogen