S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE Basic information
- Product Name:
- S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
- Synonyms:
-
- S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE
- S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-ALPHA-METHYLBENZYLAMINE
- (s)-(-)-n,n-bis(2-diphenylphosphinoethyl)-α-methylbenzylamine
- Benzenemethanamine, N,N-bis[2-(diphenylphosphino)ethyl]-α-methyl-, (S)- (9CI)
- CAS:
- 81510-19-2
- MF:
- C36H37NP2
- MW:
- 545.63
- Mol File:
- 81510-19-2.mol
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S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE Chemical Properties
- Melting point:
- 63-65 °C
- Boiling point:
- 632.8±45.0 °C(Predicted)
- pka
- 7.82±0.50(Predicted)
- form
- solid
- optical activity
- [α]20/D 4.5±0.7°, c = 1% in acetone
- BRN
- 4608384
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Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3259 8/PG 3
- WGK Germany
- 3
- F
- 1-10
MSDS
- Language:English Provider:SigmaAldrich
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S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-1-PHENYLETHYLAMINE Usage And Synthesis
General Description
(S)-(?)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones.