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4-Fluoro-3-methylphenylboronic acid

Basic information Safety Supplier Related

4-Fluoro-3-methylphenylboronic acid Basic information

Product Name:
4-Fluoro-3-methylphenylboronic acid
Synonyms:
  • 4-FLUORO-3-METHYLPHENYLBORONIC ACID
  • 4-FLUORO-M-TOLYLBORONIC ACID
  • 3-METHYL-4-FLUOROPHENYLBORONIC ACID
  • AKOS BRN-0103
  • RARECHEM AH PB 0182
  • Boronic acid, (4-fluoro-3-methylphenyl)- (9CI)
  • 4-Fluoro-3-methylphenylboronicacid~4-Fluoro-m-tolylboronicacid
  • 4-Fluoro-3-methylphenylboronic Acid (contains varying amounts of Anhydride)
CAS:
139911-27-6
MF:
C7H8BFO2
MW:
153.95
EINECS:
640-290-1
Product Categories:
  • Organoborons
  • Boronic acid
  • HALIDE
  • Aryl
  • Boronic Acids
  • Boronic Acids and Derivatives
  • Fluorin-contained phenyl boronic acid series
  • blocks
  • BoronicAcids
  • FluoroCompounds
  • Boronic Acid series
Mol File:
139911-27-6.mol
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4-Fluoro-3-methylphenylboronic acid Chemical Properties

Melting point:
212-217 °C (lit.)
Boiling point:
282.0±50.0 °C(Predicted)
Density 
1.20±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
8.71±0.10(Predicted)
form 
Crystalline Powder
color 
White to off-white
BRN 
7474834
CAS DataBase Reference
139911-27-6(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-27-37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29319090

MSDS

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4-Fluoro-3-methylphenylboronic acid Usage And Synthesis

Chemical Properties

Off-white Cryst

Uses

suzuki reaction

Uses

Reactant for:

  • Preparation of lipophilic-tailed monocationic inhibitors of neuronal nitric oxide synthase
  • Stereoselective desymmetrizing rhodium-catalyzed allylic arylation
  • Solvent free catalytic C-H functionalization reactions
  • Homocoupling reactions
  • Suzuki-Miyaura cross-coupling and Heck reactions under air

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