(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole Basic information
- Product Name:
- (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
- Synonyms:
-
- (S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole
- (S)-4-(ANTHRACEN-9-YL)-3-(T-BUTYL-2,3-DIHYDROBENZO[D][1,3]OXAPHOSPHOLE,99+%(>99%EE)[(S)-ANTPHOS]
- (S)-4-(9-Anthracenyl)-3-(tert-butyl)-2,3-dihydro-1,3-benzoxaphosphole
- (S)-AntPhos
- ZJ-0024
- 99% ee) [(S)-AntPhos]
- (S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,99+% (>
- 1,3-Benzoxaphosphole, 4-(9-anthracenyl)-3-(1,1-dimethylethyl)-2,3-dihydro-, (3S)-
- CAS:
- 1807740-34-6
- MF:
- C25H23OP
- MW:
- 370.42
- Product Categories:
-
- Chiral Phosphine
- Mol File:
- 1807740-34-6.mol
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(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole Chemical Properties
- Boiling point:
- 525.7±50.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- crystal
- color
- light yellow
- Sensitive
- air sensitive, store cold
- InChI
- InChI=1S/C25H23OP/c1-25(2,3)27-16-26-22-14-8-13-21(24(22)27)23-19-11-6-4-9-17(19)15-18-10-5-7-12-20(18)23/h4-15H,16H2,1-3H3/t27-/m1/s1
- InChIKey
- HKAWVLHXUZNLPP-HHHXNRCGSA-N
- SMILES
- O1C2=CC=CC(C3C4=CC=CC=C4C=C4C=3C=CC=C4)=C2[P@](C(C)(C)C)C1
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(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole Usage And Synthesis
Uses
(S)-AntPhos is a P-chiral monophosphorus ligand used for the asymmetric Suzuki-Miyaura and Miyaura borylation reactions. This ligand is uniquely effective for sterically hindered cross-coupling reactions.
Reactions
1. Ligand/palladium catalyst for general Miyaura borylation reactions.
2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-coupling reactions.
3. Ligand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
4. Ligand/nickel catalyst for intramolecular reductive cyclization’
5. Ligand/palladium catalyst for Dearomative cyclization’
reaction suitability
reagent type: ligand
(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphospholeSupplier
SHAOXING ZHIJUN PHARMACEUTICAL TECHNOLOGY CO.,LTD Gold
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- 0575-82126188 15395856318
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Energy Chemical
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- 021-021-58432009 400-005-6266
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Daicel Chiral Technologies (China)CO.,LTD
- Tel
- 021-50460086-9 15921403865
- han_yajun@dctc.daicel.com
Bide Pharmatech Ltd.
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- 400-164-7117 13681763483
- product02@bidepharm.com
Shanghai Haozhixiang Biotechnology Co., Ltd
- Tel
- 526763801 13301653310
- 526763801@qq.com
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(S)-4-(anthracen-9-yl)-3-(te rt-butyl)-2,3-dihydrobenzo [d][1,3]oxaphosphole(1807740-34-6)Related Product Information
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