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Chromic chloride hexahydrate

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Chromic chloride hexahydrate Basic information

Product Name:
Chromic chloride hexahydrate
Synonyms:
  • hexaaquachromium(iii)chloride
  • hexaaquachromiumchloride
  • CHROMIUM(III) CHLORIDE PURE
  • CHROMIUM(III) CHLORIDE-6-HYDRATE EXTRA PURE, U. S. P.
  • ChromiumChlorideUsp
  • Chromium(Iii)ChlorideGr
  • Chromium(Iii)Nitrate(Nonhydrate)Gr
  • Chromium(III) chloride hexahydrate, 99.998%
CAS:
10060-12-5
MF:
Cl3CrH12O6
MW:
266.45
EINECS:
629-714-6
Product Categories:
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Chromium
  • metal halide
  • chromium salt, electroplating
Mol File:
10060-12-5.mol
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Chromic chloride hexahydrate Chemical Properties

Melting point:
83 °C
Density 
1.76 g/mL at 25 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Methanol (Slightly), Water (Slightly)
form 
Powder/Solid
color 
Reddish-violet
Specific Gravity
1.76
PH
2.0-3.0
Water Solubility 
Soluble in water and alcohol. Insoluble in diethyl ether.
Sensitive 
Hygroscopic
Merck 
14,2222
Exposure limits
NIOSH: IDLH 25 mg/m3; TWA 0.5 mg/m3
Stability:
Stable, but may be air-sensitive. Hygroscopic. Incompatible with lithium, nitrogen, strong oxidizing agents.
InChIKey
LJAOOBNHPFKCDR-UHFFFAOYSA-K
CAS DataBase Reference
10060-12-5(CAS DataBase Reference)
EPA Substance Registry System
Chromium(III) chloride hexahydrate (10060-12-5)
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Safety Information

Hazard Codes 
Xn,N,C
Risk Statements 
22-36/37/38-51/53-34
Safety Statements 
24/25-61-45-36/37/39-26
RIDADR 
UN3260
WGK Germany 
1
RTECS 
GB5450000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28273985

MSDS

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Chromic chloride hexahydrate Usage And Synthesis

Chemical Properties

Chromic chloride hexahydrate is greenish-black to violet deliquescent crystals. soluble in water, ethanol, slightly soluble in acetone, insoluble in ether. It can be used as mordant, chromium additive, chromium reagent for trivalent chromium plating. It can also be used as raw material for the production of other chromium salts and chromium-containing pigments.

Uses

Chromium(III) chloride hexahydrate is used as an organic synthesis catalyst and as an additive to intravenous solutions.

Uses

Chromium(III) chloride (CrCl3. 6H2O) hexahydrate can be used:
As a source of chromium(II), which is in turn used as a catalyst in iodovinylation of aldehydes (Takai reaction).
In the synthesis of chromium(III) complexes of tetradentate Schiff bases.
In the preparation of Cr(III)-fatty acid complexes which can further be used as a catalyst for the synthesis of 1-monoacyIgIyceroIs.
In combination with choline chloride as a deep eutectic solvent, which can be utilized as a catalyst for the esterification of formic and acetic acid with alcohols.

Chromic chloride hexahydrate Preparation Products And Raw materials

Raw materials

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