ChemicalBook > Product Catalog > Organic Chemistry > Organometalate > (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Basic information
- Product Name:
- (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
- Synonyms:
-
- (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
- （1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride
- (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride
- (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride
- (r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan
- Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-
- (R,R)Jacbosen
- RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride
- CAS:
- 164931-83-3
- MF:
- C36H52ClCrN2O2
- MW:
- 632.27
- EINECS:
- 605-379-1
- Product Categories:
-
- Asymmetric Synthesis
- Chiral Catalysts, Ligands, and Reagents
- CycloadditionChiral Catalysts, Ligands, and Reagents
- Privileged Ligands and Complexes
- SALENs
- Mol File:
- 164931-83-3.mol
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Chemical Properties
- Melting point:
- >350 °C(lit.)
- form
- Powder
- color
- brown
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Usage And Synthesis
Reactions
- Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
- Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
- Catalyst for copolymerization of CO2 and epoxides.
- Catalyst for enantioselective alkylation of tributyltin enolates.
- Enantioselective addition of Me2Zn to aldehydes.
- Enantioselective intramolecular addition of tertiary enamides to ketones.
- Asymmetric iodocyclization.
- Catalytic intermolecular linear allylic C-H animation.
Uses
Catalyst used for:
- Asymmetric anti-Mannich reactions
- Coupling reactions
- Ring-opening and Diels-Alder reactions
- Allylic C-H oxidation of terminal alkenes
(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDESupplier
J & K SCIENTIFIC LTD.
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Shanghai Incat Chemtech Co.,Ltd.
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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE(164931-83-3)Related Product Information
- (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
- CHROMIUM(II) CHLORIDE
- Chromium(III) chloride
- Chromium
- (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE
- (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
- (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
- N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE
- (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
- N-benzylidenecyclohexylamine
- N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE
- N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE
- (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE
- CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE