(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE Basic information
- Product Name:
- (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
- Synonyms:
-
- (S,S)-(+)-N,N'-BIS(3,5-DI-T-BU-SALICYL.)
- (1S,2S)-(+)-1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)
- (S,S)-(+)-N,N'-BIS(3,5-DI-T-BUTYLSALICYL-IDENE)-1,2-CYCLOHEXANEDIAMINE
- (S,S)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
- (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE
- (S,S)-JACOBSEN'S LIGAND
- (S,S)-JACOBSEN LIGAND
- (1S,2S)-(+)-1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)
- CAS:
- 135616-36-3
- MF:
- C36H54N2O2
- MW:
- 546.83
- Product Categories:
-
- Aromatics
- Catalyst
- Chelating Agents & Ligands
- Intermediates
- Mol File:
- 135616-36-3.mol
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE Chemical Properties
- Melting point:
- 203-206 °C(lit.)
- alpha
- +305° (c 1, CH2Cl2)
- Boiling point:
- 619.74°C (rough estimate)
- Density
- 1.0110 (rough estimate)
- refractive index
- 1.5300 (estimate)
- storage temp.
- Inert atmosphere,Room Temperature
- pka
- 13.06±0.40(Predicted)
- form
- Powder
- color
- yellow
- optical activity
- [α]20/D +315 to 15°, c = 1 in methylene chloride
- BRN
- 5464823
- InChIKey
- FYNXDGNCEBQLGC-GTHUDTLPSA-N
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE Usage And Synthesis
Reaction
A versatile ligand for asymmetric catalysis.
(a) Conjugate addition of hydrazoic acid to unsaturated imides.
Chemical Properties
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE is yellow powder
Uses
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE is a versatile ligand used in the preparation of Jacobsen's catalyst.
Uses
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine is a chiral salen-type ligand used for preparing Jacobsen′s catalyst suitable for enantioselective epoxidation of olefins lacking functional groups.
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINESupplier
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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE(135616-36-3)Related Product Information
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