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ALLYLTRIPHENYLTIN

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ALLYLTRIPHENYLTIN Basic information

Product Name:
ALLYLTRIPHENYLTIN
Synonyms:
  • 2-propenyl-triphenylstannane
  • 2-Propenyl-triphenylstannane, Allyltriphenyltin
  • 3-(Triphenylstannyl)-1-propene
  • Triphenyl(2-propenyl)stannane
  • Triphenyl(allyl)stannane
  • Triphenylallyltin(IV)
  • tri(phenyl)-prop-2-enylstannane
  • tri(phenyl)-prop-2-enyl-stannane
CAS:
76-63-1
MF:
C21H20Sn
MW:
391.09
EINECS:
200-975-4
Product Categories:
  • Chemical Synthesis
  • Organometallic Reagents
  • Classes of Metal Compounds
  • Sn (Tin) Compounds
  • Organotin
  • Organotins
  • Typical Metal Compounds
Mol File:
76-63-1.mol
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ALLYLTRIPHENYLTIN Chemical Properties

Melting point:
71-74 °C(lit.)
Boiling point:
421.4±38.0 °C(Predicted)
Density 
1,07 g/cm3
Flash point:
>100
Water Solubility 
Insoluble in water
form 
solid
color 
White to Almost white
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
BRN 
3612762
CAS DataBase Reference
76-63-1(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
23/24/25-50/53
Safety Statements 
26-27-28-45-60-61
RIDADR 
UN 3146 6.1/PG 3
WGK Germany 
3
RTECS 
WH6705000
TSCA 
No
HS Code 
2931.90.6000
HazardClass 
6.1(b)
PackingGroup 
III

MSDS

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ALLYLTRIPHENYLTIN Usage And Synthesis

Chemical Properties

Needle-like crystals from alc.Sol in most org solvs.

Uses

Allyltriphenylstannane can be used:

  • As a reagent in the C-H phenylation of azoles catalyzed by palladium.
  • As an allylating reagent in the alkylidene Meldrum′s acids allylation catalyzed by Sc(OTf)3.
  • As a reagent in the total synthesis of an antifungal molecule (+)-ambruticin S.

Uses

Allyltriphenyltin is an insect chemosterilants.

General Description

Allyltriphenylstannane is an organotin compound, which is generally used as allylating and radical chain transfer reagent. It is also used as a source of allyl radicals.

Hazard

A poison.

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