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TRIPHENYLTIN HYDRIDE

Basic information Safety Supplier Related

TRIPHENYLTIN HYDRIDE Basic information

Product Name:
TRIPHENYLTIN HYDRIDE
Synonyms:
  • TRIPHENYLSTANNANE
  • TRIPHENYLTIN
  • TRIPHENYLTIN HYDRIDE
  • Triphenylhydridetin(IV)
  • Triphenyltin hydride,95%
  • Stannane, triphenyl-
  • triphenyl-stannan
  • Triphenylstannyl hydride
CAS:
892-20-6
MF:
C18H16Sn
MW:
351.03
EINECS:
212-967-8
Product Categories:
  • Organometallic Reagents
  • Organotin
  • OrganotinsSynthetic Reagents
  • Reduction
  • Tin Hydrides
Mol File:
892-20-6.mol
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TRIPHENYLTIN HYDRIDE Chemical Properties

Melting point:
28 °C (lit.)
Boiling point:
163-165 °C/0.3 mmHg (lit.)
Density 
1.374 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.632(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
solid
Specific Gravity
1.374
Water Solubility 
Insoluble in water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
BRN 
3544353
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference
892-20-6(CAS DataBase Reference)
EPA Substance Registry System
Triphenyltin (892-20-6)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
23/24/25-50/53
Safety Statements 
26-27-28-45-60-61
RIDADR 
UN 3077 9/PG 3
WGK Germany 
3
RTECS 
WH8882000
TSCA 
No
HazardClass 
6.1
PackingGroup 
III

MSDS

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TRIPHENYLTIN HYDRIDE Usage And Synthesis

Chemical Properties

opalescent colorless or milky white to pale yellow. Soluble in many common organic solvents; usually used in benzene or toluene.

Uses

Although the triphenyltins exhibit some curative effect, they are used mainly as protectants for control of a range of diseases, examples being early and late blights of potato and leaf spots on sugar beet and peanut.

Reactivity Profile

Triphenylstannane could be used in the reactions:
Generation of carbon radicals from selenides, halides, sulfides, and alkynes; radical deoxygenation; reduction of α,β- unsaturated aldehydes and ketones; hydrostannylation of alkynes and alkenes; reversible addition of stannyl radicals to double bonds; formation of metal triphenylstannates; reduction of aldehydes and ketones; desulfonation of β-keto phenyl sulfones; hole-transfer-promoted hydrogenation.

reaction suitability

reagent type: reductant

Synthesis

The Preparative Method of Triphenylstannane: reduction of Chlorotriphenylstannane with Lithium Aluminum Hydride in ether or with  Sodium Borohydride in glyme; reduction of bis(triphenyltin) oxide with polymethylhydrosiloxane; reduction of triphenyltin methoxide with diborane; protonation of Ph3SnLi. The reagent was also generated in situ from Ph3SnCl and Sodium Cyanoborohydride in t-butyl alcohol.

Precautions

Triphenylstannane (Ph3SnH) can be stored for several months and is easily repurified by Kugelrohr distillation (oil-pump vacuum) before use. Organotin hydrides decompose slowly at rt and are best stored at 0 °C or below.

TRIPHENYLTIN HYDRIDESupplier

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Email
market03@meryer.com
Alfa Aesar
Tel
400-6106006
Email
saleschina@alfa-asia.com
Chang Zhou Chemistar Chemistry Technology Co.,Ltd
Tel
+86 (519) 8689-6136
Email
kr@krchemistar.com
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Syntechem Co.,Ltd
Tel
Email
info@syntechem.com