TRIPHENYLTIN HYDRIDE
TRIPHENYLTIN HYDRIDE Basic information
- Product Name:
- TRIPHENYLTIN HYDRIDE
- Synonyms:
-
- TRIPHENYLSTANNANE
- TRIPHENYLTIN
- TRIPHENYLTIN HYDRIDE
- Triphenylhydridetin(IV)
- Triphenyltin hydride,95%
- Stannane, triphenyl-
- triphenyl-stannan
- Triphenylstannyl hydride
- CAS:
- 892-20-6
- MF:
- C18H16Sn
- MW:
- 351.03
- EINECS:
- 212-967-8
- Product Categories:
-
- Organometallic Reagents
- Organotin
- OrganotinsSynthetic Reagents
- Reduction
- Tin Hydrides
- Mol File:
- 892-20-6.mol
TRIPHENYLTIN HYDRIDE Chemical Properties
- Melting point:
- 28 °C (lit.)
- Boiling point:
- 163-165 °C/0.3 mmHg (lit.)
- Density
- 1.374 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.632(lit.)
- Flash point:
- >230 °F
- storage temp.
- 2-8°C
- form
- solid
- Specific Gravity
- 1.374
- Water Solubility
- Insoluble in water.
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 8: reacts rapidly with moisture, water, protic solvents
- BRN
- 3544353
- Exposure limits
- ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 - CAS DataBase Reference
- 892-20-6(CAS DataBase Reference)
- EPA Substance Registry System
- Triphenyltin (892-20-6)
Safety Information
- Hazard Codes
- T,N
- Risk Statements
- 23/24/25-50/53
- Safety Statements
- 26-27-28-45-60-61
- RIDADR
- UN 3077 9/PG 3
- WGK Germany
- 3
- RTECS
- WH8882000
- TSCA
- No
- HazardClass
- 6.1
- PackingGroup
- III
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
TRIPHENYLTIN HYDRIDE Usage And Synthesis
Chemical Properties
opalescent colorless or milky white to pale yellow. Soluble in many common organic solvents; usually used in benzene or toluene.
Uses
Although the triphenyltins exhibit some curative effect, they are used mainly as protectants for control of a range of diseases, examples being early and late blights of potato and leaf spots on sugar beet and peanut.
Reactivity Profile
Triphenylstannane could be used in the reactions:
Generation of carbon radicals from selenides, halides, sulfides, and alkynes; radical deoxygenation; reduction of α,β- unsaturated aldehydes and ketones; hydrostannylation of alkynes and alkenes; reversible addition of stannyl radicals to double bonds; formation of metal triphenylstannates; reduction of aldehydes and ketones; desulfonation of β-keto phenyl sulfones; hole-transfer-promoted hydrogenation.
reaction suitability
reagent type: reductant
Synthesis
The Preparative Method of Triphenylstannane: reduction of Chlorotriphenylstannane with Lithium Aluminum Hydride in ether or with Sodium Borohydride in glyme; reduction of bis(triphenyltin) oxide with polymethylhydrosiloxane; reduction of triphenyltin methoxide with diborane; protonation of Ph3SnLi. The reagent was also generated in situ from Ph3SnCl and Sodium Cyanoborohydride in t-butyl alcohol.
Precautions
Triphenylstannane (Ph3SnH) can be stored for several months and is easily repurified by Kugelrohr distillation (oil-pump vacuum) before use. Organotin hydrides decompose slowly at rt and are best stored at 0 °C or below.
TRIPHENYLTIN HYDRIDESupplier
- Tel
- 021-61259108 18621169109
- market03@meryer.com
- Tel
- 400-6106006
- saleschina@alfa-asia.com
- Tel
- +86 (519) 8689-6136
- kr@krchemistar.com
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Tel
- info@syntechem.com
TRIPHENYLTIN HYDRIDE(892-20-6)Related Product Information
- Fentin hydroxide
- BIS(TRIPHENYLTIN) OXIDE
- Triphenyltin acetate
- Hexaphenylditin(IV)
- Tetraphenyltin
- ALLYLTRIPHENYLTIN
- Chlorotriphenyltin
- TRIPHENYLTIN FLUORIDE
- TRIPHENYLTIN HYDRIDE
- TETRABUTYLAMMONIUM DIFLUOROTRIPHENYLSTANNATE
- TETRAPHENYL-D20-TIN
- TRI-P-TOLYLHYDROXYTIN
- triphenyltin 3,5-diisopropylsalicylate
- Decafentin
- TRIPHENYLIODOTIN
- TRI-P-TOLYLCHLOROTIN
- BIS(TRIPHENYLTIN)SULFIDE
- Tetrakis(pentafluorophenyl)stannane