Triphenyltin acetate Chemical Properties

Melting point:

118-122°C

Boiling point:

60 °C

Density 

1.55

vapor pressure 

1.9 x 10^-3 Pa (60 °C)

storage temp. 

APPROX 4°C

solubility 

Chloroform (Slightly)

form 

Powder

color 

white

Water Solubility 

28 mg/L (20 ºC)

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

Merck 

14,9745

CAS DataBase Reference

900-95-8(CAS DataBase Reference)

NIST Chemistry Reference

Triphenyl tin acetate(900-95-8)

EPA Substance Registry System

Fentin acetate (900-95-8)

Safety Information

Hazard Codes 

T+;N,N,T+

Risk Statements 

24/25-26-37/38-40-41-48/23-50/53-63

Safety Statements 

26-28-36/37/39-45-60-61

RIDADR 

3146

RTECS 

WH6650000

TSCA 

Yes

HazardClass 

6.1

PackingGroup 

III

Hazardous Substances Data

900-95-8(Hazardous Substances Data)

Toxicity

LD50 oral in rabbit: 30mg/kg

MSDS

• Language:English Provider:Acetoxytriphenylstannane
• Language:English Provider:ALFA

Triphenyltin acetate Usage And Synthesis

Uses

Triphenyltin Acetate is an organotin compound. Triphenyltin Acetate much like its hydroxide analogue is used as a fungicide and antifeeding compound for insect control. Recent studies show that Triphenyltin Acetate may have adverse effects on the reproductive and immune systems and may disrupt the endocrine system.

Uses

Fentin is a non-systemic fungicide with protective and curative action. It is used to control early and late blight in potatoes and a range of diseases in vegetables, sugar beet, peanuts, wheat, coffee, cocoa and pecans. It is also used to control algae and snails in rice fields. Fentin has previously been used as an antifoulant in marine paint.

Definition

ChEBI: An organotin compound that is the O-acetyl derivative of triphenyltin hydroxide. A fungicide used to control blights on potatoes, leaf spot diseases on sugar beet and anthracnose on beans.

General Description

A white crystalline solid. Melting point 123-131°C (253-268°F). Used as a fungicide, algaecide and molluscicide. Controls early and late blight on potatoes.

Air & Water Reactions

Slowly oxidized, hydrolyzed when exposed to air and moisture.

Reactivity Profile

ACETOXYTRIPHENYLSTANNANE is subject to decomposition when exposed to air, light and moisture [EPA, 1998].

Health Hazard

Very toxic, irritant to skin.

Fire Hazard

Avoid air, light and moisture.

Safety Profile

Poison by ingestion, intraperitoneal, intravenous, and subcutaneous routes. Moderately toxic by skin contact. Questionable carcinogen with experimental neoplastigenic data. An experimental teratogen. Other experimental reproductive effects. A fungicide and algicide used as a wood preservative. When heated to decomposition it emits acrid smoke and Sn' fumes. See also TIN COMPOUNDS.

Metabolic pathway

Fentin is degraded in soil and other biological media to give inorganic tin via the di- and mono-phenyltin compounds; often the resulting benzene is liberated. An extensive review on the metabolism and fate and behaviour of triphenyltin and its degradation products was published by Bock (1981). Fentin hydroxide has been the subject of an evaluation by the Pesticide Safety Directorate of UK MAFF (PSD, 1990).

Degradation

Fentin acetate is stable when dry but easily hydrolysed to fentin hydroxide in the presence of water. It is unstable in acids and alkalis (DT₅₀ <3 hours at pH 5, 7 or 9; 22 °C) and ionises to the triphenyltin cation. Triphenyltin compounds are converted rapidly and quantitatively into the hydroxide by alkali. Diphenyltin compounds (2) (see Scheme 1) react similarly but the hydroxide quickly loses water forming the oxide. Diphenyltin chloride initially hydrolyses to (C6H5),Sn(OH)Cl which forms compound 3 when dissociated and then the oxide is formed via dimeric intermediates. Diphenyltin compounds also split off phenyl groups as benzene (4) under the influence of water, acids or bases. Monophenyltin compounds (5) are also converted by alkali into the hydroxide which immediately loses water to form phenylstannonic acid (C6H5SnOOH) (6). In aqueous solution and at room temperature, triphenyltin compounds decompose at a slow rate, losing phenyl groups as benzene. The acetate is decomposed by sunlight and atmospheric oxygen. Phenyltin compounds are slowly decomposed by sunlight and more rapidly by UV light to give inorganic tin via the di- and mono-phenyltin compounds (PM; Bock, 1981).

Triphenyltin acetate(900-95-8)Related Product Information

• Magnesium acetate
• Ethyl acetate
• Vinyl acetate
• TRIPHENYLBORANE
• Triphenylacetic acid
• Lactulose
• Ammonium acetate
• 2,2-Diphenylacetic acid
• Cellulose acetate
• Triacetin
• Triethyl orthoacetate
• Benzyl acetate
• Trifluoroacetic acid
• Triphenylphosphine oxide
• Trimethyl orthoacetate
• Triphenylphosphine
• Fentin hydroxide
• Trifluoroacetic anhydride