TRANS-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)STYRENE Chemical Properties

Melting point:

27-33 °C(lit.)

Boiling point:

128°C/4mm

Density 

0.99±0.1 g/cm3(Predicted)

refractive index 

1.5290

Flash point:

>230 °F

storage temp. 

Inert atmosphere,Store in freezer, under -20°C

form 

Liquid

color 

Clear colorless to pale yellow

BRN 

8617179

InChI

InChI=1S/C14H19BO2/c1-13(2)14(3,4)17-15(16-13)11-10-12-8-6-5-7-9-12/h5-11H,1-4H3/b11-10+

InChIKey

ARAINKADEARZLZ-ZHACJKMWSA-N

SMILES

O1C(C)(C)C(C)(C)OB1/C=C/C1=CC=CC=C1

CAS DataBase Reference

83947-56-2(CAS DataBase Reference)

Safety Information

WGK Germany 

3

HS Code 

29310099

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

TRANS-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)STYRENE Usage And Synthesis

Uses

Reactant for:

• Oxidative coupling reactions catalyzed by areneruthenium
• Cycloaddition reactions
• Preparation of allyl vinyl ethers via Cu-catalyzed coupling with alcohols
• Preparation of 5-vinyl-3-pyridinecarbonitriles as PKCθ inhibitors
• Diastereoselective addition to zincated hydrazones and stereospecific trapping of boron/zinc bimetallic intermediates by carbon electrophiles
• Regioselective and stereoselective Pd-catalyzed chelate-controlled intermolecular oxidative Heck reactions

TRANS-2-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)STYRENE(83947-56-2)Related Product Information

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