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2-Acrylamide-2-methylpropanesulfonic acid

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2-Acrylamide-2-methylpropanesulfonic acid Basic information

Product Name:
2-Acrylamide-2-methylpropanesulfonic acid
Synonyms:
  • 1-Propanesulfonicacid,2-methyl-2-[(1-oxo-2-propenyl)amino]-
  • 2-Acrylamido-2-methyl-1-propane
  • 2-acrylamido-2-methylpropanesulfonate
  • 1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-
  • 2-ACRYLAMIDE-2-METHYLPROPANESULFONIC ACID
  • 2-ACRYLAMIDO-2-METHYL-1-PROPANESULFONIC ACID
  • 2-ACRYLAMIDO-2-METHYLPROPANESULFONIC ACID
  • 2-ACRYLAMIDO-2-METHYLPROPANESULPHONIC ACID
CAS:
15214-89-8
MF:
C7H13NO4S
MW:
207.25
EINECS:
239-268-0
Product Categories:
  • Organic Chemicals
  • Industrial/Fine Chemicals
  • monomer
  • Acrylamide and Methacrylamide
  • Acrylic Monomers
  • Monomers
  • bc0001
  • 15214-89-8
Mol File:
15214-89-8.mol
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2-Acrylamide-2-methylpropanesulfonic acid Chemical Properties

Melting point:
195 °C (dec.) (lit.)
Density 
1.45
vapor pressure 
<0.0000004 hPa (25 °C)
refractive index 
1.6370 (estimate)
Flash point:
160 °C
storage temp. 
Store below +30°C.
solubility 
>500g/l soluble
pka
1.67±0.50(Predicted)
form 
solution
color 
White
Water Solubility 
1500 g/L (20 ºC)
Sensitive 
Hygroscopic
BRN 
1946464
Stability:
Light Sensitive
InChIKey
HNKOEEKIRDEWRG-UHFFFAOYSA-N
LogP
-3.7 at 20℃ and pH1-7
Surface tension
70.5mN/m at 1g/L and 20℃
Dissociation constant
2.4 at 20℃
CAS DataBase Reference
15214-89-8(CAS DataBase Reference)
EPA Substance Registry System
1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propenyl)amino]- (15214-89-8)
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Safety Information

Hazard Codes 
C,Xn
Risk Statements 
34-21/22-41-37-20/22
Safety Statements 
26-36/37/39-45-22
RIDADR 
UN 2585 8/PG 3
WGK Germany 
1
RTECS 
TZ6658000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29241900
Toxicity
LD50 orally in Rabbit: 1000 - 2000 mg/kg

MSDS

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2-Acrylamide-2-methylpropanesulfonic acid Usage And Synthesis

Chemical Properties

2-Acrylamide-2-methylpropanesulfonic acid is a white crystals. The melting point is 195°C (decomposition). Soluble in water, the solution is acidic. Soluble in dimethylformamide, partially soluble in methanol, ethanol, insoluble in acetone. Slightly sour.

Uses

2-Acrylamide-2-methylpropanesulfonic acid has good complexion, adsorption, biological activity, surface activity, hydrolysis stability and thermal stability. It can be used in oil chemical, water treatment, synthetic fiber, printing and dyeing, plastics, water absorbing coatings, paper, bio-medical, magnetic materials and cosmetics industries.

Preparation

2-Acrylamido-2-methylpropanesulfonic acid(AMPS) can be synthesized by one step and two steps. The one-step method is to react the raw materials acrylonitrile, isobutylene and oleum together. The two-step method is to sulfonate isobutylene in the presence of a reaction solvent to obtain a sulfonated intermediate, and then react with acrylonitrile in the presence of sulfuric acid. One-step method is more economical. Raw material consumption quota: isobutylene 300kg/t, acrylonitrile 290kg/t, oleum 560kg/t.

Application

2-Acrylamide-2-methylpropanesulfonic acid is an important monomer. Its copolymers or homopolymers with different molecular weight can be widely used in textile, oil drilling, water treatment, papermaking, dying, coating, cosmetics, electronics, etc. because of its unique formular structure—containing sulfonic acid group and unsaturated radical, thus showing excellent properties in many aspects.

Definition

ChEBI: 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid is an organosulfonic acid.

Solubility in organics

DMF, methanol (@ 65C), water

2-Acrylamide-2-methylpropanesulfonic acid Preparation Products And Raw materials

Raw materials

2-Acrylamide-2-methylpropanesulfonic acidSupplier

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