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Tetraallyltin

Basic information Safety Supplier Related

Tetraallyltin Basic information

Product Name:
Tetraallyltin
Synonyms:
  • tetrallylstannane
  • Tetraallyltin,min.95%
  • Tetraallyltin, 95+%
  • Tetraallylstannane, Tetraallyltin
  • Tetraallyltin 97%
  • Tetraallyltin, min. 95%
  • Tetraallyltin,97%
  • TETRAALLYLSTANNANE
CAS:
7393-43-3
MF:
C12H20Sn
MW:
283
EINECS:
230-987-5
Product Categories:
  • Classes of Metal Compounds
  • Sn (Tin) Compounds
  • Typical Metal Compounds
  • organotin compound
Mol File:
7393-43-3.mol
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Tetraallyltin Chemical Properties

Boiling point:
69-70 °C1.5 mm Hg(lit.)
Density 
1.179 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.539(lit.)
Flash point:
167 °F
form 
Liquid
Specific Gravity
1.179
color 
Clear colorless
Water Solubility 
Not miscible in water or difficult to mix.
Sensitive 
Air Sensitive
BRN 
3536269
Exposure limits
ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3
CAS DataBase Reference
7393-43-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
T
Risk Statements 
23/24/25
Safety Statements 
23-24/25-45-36/37
RIDADR 
UN 2788 6.1/PG 3
WGK Germany 
3
10-23
TSCA 
No
HazardClass 
6.1
PackingGroup 
II
HS Code 
29310099

MSDS

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Tetraallyltin Usage And Synthesis

Chemical Properties

Clear Colorless liquid

Uses

Applied as allyl transfer reagent.

Purification Methods

Possible contaminants are allyl chloride and allyltin chloride. Check the 1H NMR and IR [Fishwick & Wallbridge J Organomet Chem 25 69 1970], and if impure, dissolve it in Et2O and shake it with a 5% aqueous solution of NaF which precipitates allyltin fluoride. Separate the Et2O layer, dry (MgSO4) and distil it at ~ 0.2mm. It decomposes slightly on repeated distillation. [O'Brien et al. Inorg Synth XIII 75 1972, Fishwick et al. J Chem Soc (A) 57 1971, Beilstein 4 III 1922.]

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