ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organotin > Tetraallyltin
Tetraallyltin
Tetraallyltin Basic information
- Product Name:
- Tetraallyltin
- Synonyms:
-
- tetrallylstannane
- Tetraallyltin,min.95%
- Tetraallyltin, 95+%
- Tetraallylstannane, Tetraallyltin
- Tetraallyltin 97%
- Tetraallyltin, min. 95%
- Tetraallyltin,97%
- TETRAALLYLSTANNANE
- CAS:
- 7393-43-3
- MF:
- C12H20Sn
- MW:
- 283
- EINECS:
- 230-987-5
- Product Categories:
-
- Classes of Metal Compounds
- Sn (Tin) Compounds
- Typical Metal Compounds
- organotin compound
- Mol File:
- 7393-43-3.mol
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Tetraallyltin Chemical Properties
- Boiling point:
- 69-70 °C1.5 mm Hg(lit.)
- Density
- 1.179 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.539(lit.)
- Flash point:
- 167 °F
- form
- Liquid
- Specific Gravity
- 1.179
- color
- Clear colorless
- Water Solubility
- Not miscible in water or difficult to mix.
- Sensitive
- Air Sensitive
- BRN
- 3536269
- Exposure limits
- ACGIH: TWA 0.1 mg/m3; STEL 0.2 mg/m3 (Skin)
NIOSH: IDLH 25 mg/m3; TWA 0.1 mg/m3 - CAS DataBase Reference
- 7393-43-3(CAS DataBase Reference)
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Safety Information
- Hazard Codes
- T
- Risk Statements
- 23/24/25
- Safety Statements
- 23-24/25-45-36/37
- RIDADR
- UN 2788 6.1/PG 3
- WGK Germany
- 3
- F
- 10-23
- TSCA
- No
- HazardClass
- 6.1
- PackingGroup
- II
- HS Code
- 29310099
MSDS
- Language:English Provider:ACROS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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Tetraallyltin Usage And Synthesis
Chemical Properties
Clear Colorless liquid
Uses
Applied as allyl transfer reagent.
Purification Methods
Possible contaminants are allyl chloride and allyltin chloride. Check the 1H NMR and IR [Fishwick & Wallbridge J Organomet Chem 25 69 1970], and if impure, dissolve it in Et2O and shake it with a 5% aqueous solution of NaF which precipitates allyltin fluoride. Separate the Et2O layer, dry (MgSO4) and distil it at ~ 0.2mm. It decomposes slightly on repeated distillation. [O'Brien et al. Inorg Synth XIII 75 1972, Fishwick et al. J Chem Soc (A) 57 1971, Beilstein 4 III 1922.]
TetraallyltinSupplier
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