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TETRAETHYLTIN

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TETRAETHYLTIN Basic information

Product Name:
TETRAETHYLTIN
Synonyms:
  • TETRAETHYLTIN
  • TIN TETRAETHYL
  • (C2H5)4Sn
  • tetraethyl-stannan
  • Tetraethylstannane
  • tetraethyl-Stannane
  • tetraethyl-ti
  • C40.9%,H8.5%
CAS:
597-64-8
MF:
C8H20Sn
MW:
234.95
EINECS:
209-906-2
Product Categories:
  • Organometallic Reagents
  • Organotin
  • Organotins
Mol File:
597-64-8.mol
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TETRAETHYLTIN Chemical Properties

Melting point:
−112 °C(lit.)
Boiling point:
181 °C(lit.)
Density 
1.187 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.473(lit.)
Flash point:
128 °F
storage temp. 
Refrigerator (+4°C) + Poison room
solubility 
Chloroform (Sparingly), Methanol (Slightly)
form 
Liquid
Specific Gravity
1.187
Water Solubility 
Insoluble in water. Soluble in alcohol and ether
Dielectric constant
2.7999999999999998
CAS DataBase Reference
597-64-8(CAS DataBase Reference)
EPA Substance Registry System
Tetraethyltin (597-64-8)
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Safety Information

Hazard Codes 
T+,N
Risk Statements 
26/27/28-50/53
Safety Statements 
26-27-28-45-60-61
RIDADR 
UN 3384 6.1/PG 1
WGK Germany 
2
RTECS 
WH8625000
TSCA 
No
HazardClass 
6.1
PackingGroup 
II
HS Code 
29310099
Hazardous Substances Data
597-64-8(Hazardous Substances Data)

MSDS

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TETRAETHYLTIN Usage And Synthesis

Chemical Properties

clear colorless liquid

Chemical Properties

Tetraethyltin is a colorless organotin liquid.

Uses

Tetraethyltin is used as catalyst for olefin polymerization and to produce other organotin compounds. It is also used in the electronics industry and as a preservative for wood, textiles, paper, and leather.

General Description

Colorless liquid. Used as biocides, bactericides, fungicides and insecticides; preservatives for wood, textile, paper, and leather. Not registered as a pesticide in the U.S.

Air & Water Reactions

TETRAETHYLTIN tends to ignite in air.

Reactivity Profile

When heated to decomposition, TETRAETHYLTIN emits acrid smoke and fumes. (nonspecific -- Organic Tin Compounds) Avoid strong oxidizers. [EPA, 1998].

Hazard

Toxic material.

Health Hazard

Toxic hazard rating is high for oral, intravenous, intraperitoneal administration. TETRAETHYLTIN causes swelling of the brain and spinal cord.

Fire Hazard

When heated to decomposition, TETRAETHYLTIN emits acrid smoke and fumes. (Non-Specific -- Organic Tin Compounds) Avoid strong oxidizers.

Safety Profile

Poison by ingestion, intravenous, and intraperitoneal routes. When heated to decomposition it emits acrid smoke and irritating fumes. See also TIN COMPOUNDS.

Potential Exposure

Used as biocide, bactericide, fungicide and insecticide; preservative for wood, textile, paper, and leather. Not registered as a pesticide in the United States.

Shipping

UN3384 Toxic by inhalation liquid, flammable, n.o.s. with an LC50 ≤1000 mL/m3 and saturated vapor concentration ≥ to 10 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone B. UN2788Organotin compounds, liquid, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.

Waste Disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

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