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DI-TERT-BUTYLCYCLOPENTADIENE

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DI-TERT-BUTYLCYCLOPENTADIENE Basic information

Product Name:
DI-TERT-BUTYLCYCLOPENTADIENE
Synonyms:
  • di-tert-butylcyclopentadiene, mixture of isomers
  • DI-TERT-BUTYLCYCLOPENTADIENE
  • 2,5-Bis(2-methyl-2-propanyl)-1,3-cyclopentadiene
  • DI-TERT-BUTYLCYCLOPENTADIENE ISO 9001:2015 REACH
CAS:
120937-44-2
MF:
C13H22
MW:
178.31
Product Categories:
  • Alkenes
  • Cyclic
  • Organic Building Blocks
Mol File:
120937-44-2.mol
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DI-TERT-BUTYLCYCLOPENTADIENE Chemical Properties

Melting point:
69 °C
Density 
0.836 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.467
Flash point:
9 °C
storage temp. 
2-8°C
BRN 
3537135
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Safety Information

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-26-36
RIDADR 
UN 3295 3/PG 2
WGK Germany 
3
10

MSDS

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DI-TERT-BUTYLCYCLOPENTADIENE Usage And Synthesis

Uses

Di-tert-butylcyclopentadiene may be used in the preparation of 2,5,4′,6′-tetra-tert-butyl-5′H-spirocyclopentane-1,2′-cyclopenta[b][1,3]diselena-2,4-diene and 1,3,5,7-tetra-tert-butyl-3a,7a-dihydro-3a,7a-epi-selenodicyclopenta[b,e][1,4]diselenine.

General Description

Preparation of di-tert-butylcyclopentadiene by phase-transfer-catalyzed alkylation has been reported. It reacts with excess potassium tert-butoxide in the presence of elemental selenium to yield cyclopentadienes bridged by two or three selenium atoms through one or two diselenoketal functionalities. It reacts with excess potassium tert-butoxide in the presence of elemental sulfur to yield cyclopentadienes bridged by sulfur atoms via one or two dithioketal functionalities.

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