ChemicalBook > Product Catalog > Organic Chemistry > Hydrocarbons and derivatives > Cyclic hydrocarbons > DI-TERT-BUTYLCYCLOPENTADIENE
DI-TERT-BUTYLCYCLOPENTADIENE
DI-TERT-BUTYLCYCLOPENTADIENE Basic information
- Product Name:
- DI-TERT-BUTYLCYCLOPENTADIENE
- Synonyms:
-
- di-tert-butylcyclopentadiene, mixture of isomers
- DI-TERT-BUTYLCYCLOPENTADIENE
- 2,5-Bis(2-methyl-2-propanyl)-1,3-cyclopentadiene
- DI-TERT-BUTYLCYCLOPENTADIENE ISO 9001:2015 REACH
- CAS:
- 120937-44-2
- MF:
- C13H22
- MW:
- 178.31
- Product Categories:
-
- Alkenes
- Cyclic
- Organic Building Blocks
- Mol File:
- 120937-44-2.mol
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DI-TERT-BUTYLCYCLOPENTADIENE Chemical Properties
- Melting point:
- 69 °C
- Density
- 0.836 g/mL at 20 °C (lit.)
- refractive index
- n20/D 1.467
- Flash point:
- 9 °C
- storage temp.
- 2-8°C
- BRN
- 3537135
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Safety Information
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38
- Safety Statements
- 16-26-36
- RIDADR
- UN 3295 3/PG 2
- WGK Germany
- 3
- F
- 10
MSDS
- Language:English Provider:SigmaAldrich
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DI-TERT-BUTYLCYCLOPENTADIENE Usage And Synthesis
Uses
Di-tert-butylcyclopentadiene may be used in the preparation of 2,5,4′,6′-tetra-tert-butyl-5′H-spirocyclopentane-1,2′-cyclopenta[b][1,3]diselena-2,4-diene and 1,3,5,7-tetra-tert-butyl-3a,7a-dihydro-3a,7a-epi-selenodicyclopenta[b,e][1,4]diselenine.
General Description
Preparation of di-tert-butylcyclopentadiene by phase-transfer-catalyzed alkylation has been reported. It reacts with excess potassium tert-butoxide in the presence of elemental selenium to yield cyclopentadienes bridged by two or three selenium atoms through one or two diselenoketal functionalities. It reacts with excess potassium tert-butoxide in the presence of elemental sulfur to yield cyclopentadienes bridged by sulfur atoms via one or two dithioketal functionalities.
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