Indium chloride Chemical Properties

Melting point:

262 °C (dec.)(lit.)

Boiling point:

300°C

Density 

3.46 g/mL at 25 °C(lit.)

vapor pressure 

1Pa at 25℃

Flash point:

300°C subl.

storage temp. 

Inert atmosphere,Room Temperature

solubility 

Water (Slightly)

form 

powder

color 

White to off-white

Specific Gravity

3.46

Water Solubility 

reacts

Sensitive 

Hygroscopic

Merck 

14,4958

Exposure limits

ACGIH: TWA 0.1 mg/m3
NIOSH: TWA 0.1 mg/m3

Stability:

hygroscopic

InChIKey

PSCMQHVBLHHWTO-UHFFFAOYSA-K

LogP

5.9 at 22℃

CAS DataBase Reference

10025-82-8(CAS DataBase Reference)

NIST Chemistry Reference

Indium trichloride(10025-82-8)

EPA Substance Registry System

Indium chloride (InCl3) (10025-82-8)

Safety Information

Hazard Codes 

C

Risk Statements 

36/37/38-34-29-22

Safety Statements 

26-36/37/39-45

RIDADR 

UN 3260 8/PG 2

WGK Germany 

3

RTECS 

NL1400000

F 

3-10

TSCA 

Yes

HazardClass 

8

PackingGroup 

III

HS Code 

28273990

Hazardous Substances Data

10025-82-8(Hazardous Substances Data)

Toxicity

MLD s.c. in rats: 10.2 mg/kg; MLD i.v. in rabbits: 0.64 mg/kg, McCord et al., J. Ind. Hyg. Toxicol. 24, 243 (1942)

MSDS

• Language:English Provider:Indium chloride
• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

Indium chloride Usage And Synthesis

Description

Indium chloride is a useful catalyst for aqueous organic reactions including C-C bond formation, aldol reaction, Friedel-Crafts acylation, Diels-Alder reaction and reduction1-4. It is an efficient, mild, Lewis acid for organic synthesis. It is an efficient catalyst for thioacetalization and its chemoselectivity. It can also catalyze the enantioselective ring-opening of meso-aziridines with thiols. Moreover, it can act as a highly efficient catalyst in water for the preparation of furyl glycosides.

Chemical Properties

white crystalline powder

Uses

Catalyzes the enantioselective ring-opening of meso-aziridines with thiols.1,2 A highly efficient catalyst in water for the preparation of furyl glycosides.3

Uses

Indium(III) chloride is used as catalyst for aqueous organic reactions including C-C bond formation, aldol reactions, and reductions and for organic synthesis.

Uses

In electroplating using a solution of the salt with dextrose and NaCN. This solution is stable, though it turns dark on standing and deposits a mud which, however, contains no indium.

General Description

Indium(III) chloride (InCl₃) is an indium halide that is a Lewis acid in a variety of organic reactions.

Hazard

See indium.

Purification Methods

The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.]

Indium chloride(10025-82-8)Related Product Information

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