Indium chloride
Description- Product Name
- Indium chloride
- CAS No.
- 10025-82-8
- Chemical Name
- Indium chloride
- Synonyms
- InCl3;Indium trichloride;Indium chloride (InCl3);Indiclor;Indium (III) chloride;Cu(II) oxide;Indium trichL;Indium Choride;INDIUM CHLORIDE;Trichloroindium
- CBNumber
- CB3750120
- Molecular Formula
- Cl3In
- Formula Weight
- 221.18
- MOL File
- 10025-82-8.mol
Indium chloride Property
- Melting point:
- 262 °C (dec.)(lit.)
- Boiling point:
- 300°C
- Density
- 3.46 g/mL at 25 °C(lit.)
- vapor pressure
- 1Pa at 25℃
- Flash point:
- 300°C subl.
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- Water (Slightly)
- form
- powder
- color
- White to off-white
- Specific Gravity
- 3.46
- Water Solubility
- reacts
- Sensitive
- Hygroscopic
- Crystal Structure
- AlCl3 type
- crystal system
- Monoclinic
- Merck
- 14,4958
- Space group
- C2/m
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.641 1.11 0.631 90 109.8 90 0.422 - Exposure limits
- ACGIH: TWA 0.1 mg/m3
NIOSH: TWA 0.1 mg/m3 - Stability:
- hygroscopic
- InChIKey
- PSCMQHVBLHHWTO-UHFFFAOYSA-K
- LogP
- 5.9 at 22℃
- CAS DataBase Reference
- 10025-82-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Indium trichloride(10025-82-8)
- EPA Substance Registry System
- Indium chloride (InCl3) (10025-82-8)
Safety
- Hazard Codes
- C
- Risk Statements
- 36/37/38-34-29-22
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3260 8/PG 2
- WGK Germany
- 3
- RTECS
- NL1400000
- F
- 3-10
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 28273990
- Hazardous Substances Data
- 10025-82-8(Hazardous Substances Data)
- Toxicity
- MLD s.c. in rats: 10.2 mg/kg; MLD i.v. in rabbits: 0.64 mg/kg, McCord et al., J. Ind. Hyg. Toxicol. 24, 243 (1942)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H372Causes damage to organs through prolonged or repeated exposure
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P314Get medical advice/attention if you feel unwell.
N-Bromosuccinimide Price
- Product number
- 203440
- Product name
- Indium(III) chloride
- Purity
- 99.999% trace metals basis
- Packaging
- 1g
- Price
- $45.1
- Updated
- 2024/03/01
- Product number
- 203440
- Product name
- Indium(III) chloride
- Purity
- 99.999% trace metals basis
- Packaging
- 10g
- Price
- $197
- Updated
- 2024/03/01
- Product number
- I0778
- Product name
- Indium(III) Chloride Anhydrous
- Purity
- >99.0%(T)
- Packaging
- 5g
- Price
- $47
- Updated
- 2024/03/01
- Product number
- I0778
- Product name
- Indium(III) Chloride Anhydrous
- Purity
- >99.0%(T)
- Packaging
- 25g
- Price
- $140
- Updated
- 2024/03/01
- Product number
- 011856
- Product name
- Indium(III) chloride, anhydrous, 99.999% (metals basis)
- Packaging
- 1g
- Price
- $44.5
- Updated
- 2023/06/20
Indium chloride Chemical Properties,Usage,Production
Description
Indium chloride is a useful catalyst for aqueous organic reactions including C-C bond formation, aldol reaction, Friedel-Crafts acylation, Diels-Alder reaction and reduction1-4. It is an efficient, mild, Lewis acid for organic synthesis. It is an efficient catalyst for thioacetalization and its chemoselectivity. It can also catalyze the enantioselective ring-opening of meso-aziridines with thiols. Moreover, it can act as a highly efficient catalyst in water for the preparation of furyl glycosides.
Chemical Properties
white crystalline powder
Hygroscopic. Decomposes in
water to InCl3 and In. M.p. 235°C; decomposes below the m.p.,
apparently to InCl3 and InCl; b.p. ~570°C; d 3.65. Rhombic
crystals.
Uses
Indium chloride is used as catalyst for aqueous organic reactions including C-C bond formation, aldol reactions, and reductions and for organic synthesis. In electroplating using a solution of the salt with dextrose and NaCN.
Production Methods
According to Klemm, metallic In is oxidized in InCl3 in a stream of Cl2, which has been carefully dried with concentrated H2SO4 and P2O5. A thoroughly dried quartz apparatus whose components have been fused or connected by ground joints is used. Chlorination proceeds rather vigorously at first, with a pale glow, and it proceeds through the mono- and dichloride steps. These compounds are melts. The end product of the chlorination, InCl3, sublimes around 600°C as lustrous spangles which appear on the walls of the receiver. The Indium chloride (LnCl3) may be purified by subliming in a stream of N2 (or CO2) to which some Cl2 has been added. The sublimate can cool in a stream of inert, Cl2-free gas to remove excess chlorine.
General Description
Indiumchloride (InCl3) is an indium halide that is a Lewis acid in a variety of organic reactions.
Purification Methods
The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.]
Indium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Indium chloride manufacturers
- Product
- Indium chloride 10025-82-8
- Price
- US $30.00-10.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-11-03
- Product
- Indium chloride 10025-82-8
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2022-09-27
- Product
- Indium chloride 10025-82-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2023-02-01