Description
ChemicalBook > CAS DataBase List > Indium chloride

Indium chloride

Description
Product Name
Indium chloride
CAS No.
10025-82-8
Chemical Name
Indium chloride
Synonyms
InCl3;Indium trichloride;Indium chloride (InCl3);Indiclor;Indium (III) chloride;Cu(II) oxide;Indium trichL;Indium Choride;INDIUM CHLORIDE;Trichloroindium
CBNumber
CB3750120
Molecular Formula
Cl3In
Formula Weight
221.18
MOL File
10025-82-8.mol
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Indium chloride Property

Melting point:
262 °C (dec.)(lit.)
Boiling point:
300°C
Density 
3.46 g/mL at 25 °C(lit.)
vapor pressure 
1Pa at 25℃
Flash point:
300°C subl.
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Water (Slightly)
form 
powder
color 
White to off-white
Specific Gravity
3.46
Water Solubility 
reacts
Sensitive 
Hygroscopic
Crystal Structure
AlCl3 type
crystal system
Monoclinic
Merck 
14,4958
Space group
C2/m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.6411.110.63190109.8900.422
Exposure limits
ACGIH: TWA 0.1 mg/m3
NIOSH: TWA 0.1 mg/m3
Stability:
hygroscopic
InChIKey
PSCMQHVBLHHWTO-UHFFFAOYSA-K
LogP
5.9 at 22℃
CAS DataBase Reference
10025-82-8(CAS DataBase Reference)
NIST Chemistry Reference
Indium trichloride(10025-82-8)
EPA Substance Registry System
Indium chloride (InCl3) (10025-82-8)
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Safety

Hazard Codes 
C
Risk Statements 
36/37/38-34-29-22
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3260 8/PG 2
WGK Germany 
3
RTECS 
NL1400000
F 
3-10
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
28273990
Hazardous Substances Data
10025-82-8(Hazardous Substances Data)
Toxicity
MLD s.c. in rats: 10.2 mg/kg; MLD i.v. in rabbits: 0.64 mg/kg, McCord et al., J. Ind. Hyg. Toxicol. 24, 243 (1942)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H372Causes damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
203440
Product name
Indium(III) chloride
Purity
99.999% trace metals basis
Packaging
1g
Price
$45.1
Updated
2024/03/01
Sigma-Aldrich
Product number
203440
Product name
Indium(III) chloride
Purity
99.999% trace metals basis
Packaging
10g
Price
$197
Updated
2024/03/01
TCI Chemical
Product number
I0778
Product name
Indium(III) Chloride Anhydrous
Purity
>99.0%(T)
Packaging
5g
Price
$47
Updated
2024/03/01
TCI Chemical
Product number
I0778
Product name
Indium(III) Chloride Anhydrous
Purity
>99.0%(T)
Packaging
25g
Price
$140
Updated
2024/03/01
Alfa Aesar
Product number
011856
Product name
Indium(III) chloride, anhydrous, 99.999% (metals basis)
Packaging
1g
Price
$44.5
Updated
2023/06/20
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Indium chloride Chemical Properties,Usage,Production

Description

Indium chloride is a useful catalyst for aqueous organic reactions including C-C bond formation, aldol reaction, Friedel-Crafts acylation, Diels-Alder reaction and reduction1-4. It is an efficient, mild, Lewis acid for organic synthesis. It is an efficient catalyst for thioacetalization and its chemoselectivity. It can also catalyze the enantioselective ring-opening of meso-aziridines with thiols. Moreover, it can act as a highly efficient catalyst in water for the preparation of furyl glycosides.

Chemical Properties

white crystalline powder
Hygroscopic. Decomposes in water to InCl3 and In. M.p. 235°C; decomposes below the m.p., apparently to InCl3 and InCl; b.p. ~570°C; d 3.65. Rhombic crystals.

Uses

Indium chloride is used as catalyst for aqueous organic reactions including C-C bond formation, aldol reactions, and reductions and for organic synthesis. In electroplating using a solution of the salt with dextrose and NaCN.

Production Methods

According to Klemm, metallic In is oxidized in InCl3 in a stream of Cl2, which has been carefully dried with concentrated H2SO4 and P2O5. A thoroughly dried quartz apparatus whose components have been fused or connected by ground joints is used. Chlorination proceeds rather vigorously at first, with a pale glow, and it proceeds through the mono- and dichloride steps. These compounds are melts. The end product of the chlorination, InCl3, sublimes around 600°C as lustrous spangles which appear on the walls of the receiver. The Indium chloride (LnCl3) may be purified by subliming in a stream of N2 (or CO2) to which some Cl2 has been added. The sublimate can cool in a stream of inert, Cl2-free gas to remove excess chlorine.

General Description

Indiumchloride (InCl3) is an indium halide that is a Lewis acid in a variety of organic reactions.

Purification Methods

The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.]

Indium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Indium chloride manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Indium chloride 10025-82-8
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-11-03
Hebei Weibang Biotechnology Co., Ltd
Product
Indium chloride 10025-82-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-09-27
Hebei Weibang Biotechnology Co., Ltd
Product
Indium chloride 10025-82-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-02-01

10025-82-8, Indium chlorideRelated Search:

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