methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate
methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Basic information
- Product Name:
- methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate
- Synonyms:
-
- Demagnesia chloric acid -a methyl ester
- Chlorophyll Impurity 1
- methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate
- methylpheophorbide
- PHEOPHORBIDEAMETHYLESTER
- (3S)-9-Ethenyl-14-ethyl-21α-methoxycarbonyl-4α,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoic acid methyl ester
- Methyl pheophorbide a
- Methylphaeophorbide a
- CAS:
- 5594-30-9
- MF:
- C36H38N4O5
- MW:
- 606.71
- EINECS:
- 227-007-3
- Mol File:
- 5594-30-9.mol
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methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Chemical Properties
- Melting point:
- 226-228 °C
- Boiling point:
- 956.2±65.0 °C(Predicted)
- Density
- 1.244±0.06 g/cm3(Predicted)
- form
- Solid
- color
- Brown to black
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methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate Usage And Synthesis
Uses
Methyl pheophorbide a is a natural product, one of the chlorophyll-a derivatives[1][2].
References
[1] F.C. Pennington, et al. Preparation and Properties of Pyrochlorophyll a, Methyl Pyrochlorophyllide a, Pyropheophytin a, and Methyl Pyropheophorbide a Derived from Chlorophyll by Decarbomethoxylation. J. Am. Chem. Soc. 1964, 86, 7, 1418-1426.
[2] ShinOgasawara, et al. C132-Methylation of methyl pheophorbide a and stereoselective preparation of methyl (132R)-methylpyropheophorbide a. Tetrahedron Letters, 2014, 3618-3621.
[3] Ha J Y, et al. Isolation, identification, and apoptosis activity of the photosensitizer methyl pheophorbide A from Perilla frutescens leaves[J]. Applied Biological Chemistry, 2022, 65(1): 52.
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