(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine Basic information
- Product Name:
- (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
- Synonyms:
-
- (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
- (1R)-trans-N-Boc-1,2-diaminocyclohexane
- Trans (1R,2R)-1N-Boc-cyclohexane-1,2-diamine
- Carbamic acid, N-[(1R,2R)-2-aminocyclohexyl]-, 1,1-dimethylethyl ester
- N-Boc-1R,2R-Cyclohexanediamine
- ((1R,2R)-2-Aminocyclohexyl)-carbamic acid tert-butyl ester
- (1R,2R)-(-)-N-(t-Butoxycarbonyl)-1,2-cyclohexanediamine
- (1R,2R)-N-tert.-Butoxycarbonylcyclohexane-1,2-diamine
- CAS:
- 146504-07-6
- MF:
- C11H22N2O2
- MW:
- 214.3
- Mol File:
- 146504-07-6.mol
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(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine Chemical Properties
- Melting point:
- 114-115℃
- Boiling point:
- 322.1±31.0 °C(Predicted)
- Density
- 1.02±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- powder to crystal
- pka
- 12.26±0.40(Predicted)
- color
- White to Almost white
- optical activity
- [α]/D -26±2°, c = 1 in chloroform
- BRN
- 7023564
- InChIKey
- AKVIZYGPJIWKOS-RKDXNWHRSA-N
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Safety Information
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 3259 8/PG 3
- WGK Germany
- 3
- HazardClass
- 8
- PackingGroup
- Ⅲ
- HS Code
- 29242990
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(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine Usage And Synthesis
Chemical Properties
White powder
Uses
(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:
- An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
- A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.
Definition
ChEBI: (1R,2R)-trans-N-Boc-1,2-cyclohexanediamine is an amine.
(1R,2R)-trans-N-Boc-1,2-CyclohexanediamineSupplier
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(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine(146504-07-6)Related Product Information
- CIS-(1R,2S)-1N-CBZ-CYCLOHEXANE-1,2-DIAMINE
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- (1R,2R)-N,N'-DI-P-TOLUENESULFONYL-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE
- N-Boc-(1S, 2R)-diaminocyclohexane (R)-Hydroxyphenylaceticacid salt|||
- (S)-(-)-α,α-Diphenyl-2-pyrrolidinemethanol
- (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine
- (1R,2R)-(+)-1,2-Diphenylethylenediamine
- (1S,2S)-(-)-N-(4-TOLUENESULPHONYL)-1,2-DIAMINOCYCLOHEXANE
- (1S,2S)-N,N'-DI-P-TOLUENESULFONYL-1,2-DIPHENYL-1,2-ETHYLENEDIAMINE
- (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine
- (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
- (R)-(+)-a,a-Diphenyl-2-pyrrolidinemethanol
- N-Boc-1,2-Diaminocyclohexane
- 1,2-Diaminocyclohexane
- 1-N-BOC-1,2-TRANS-CYCLOHEXYLDIAMINE
- (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
- (1R,2R)-N,N''-BIS-BOC-CYCLOHEXANE-1,2-DIAMINE
- (4AR,8AR)-OCTAHYDRO-QUINOXALINE-1-CARBOXYLIC ACID TERT-BUTYL ESTER