Basic information Safety Supplier Related

(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine

Basic information Safety Supplier Related

(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine Basic information

Product Name:
(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
Synonyms:
  • (1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine
  • (1R)-trans-N-Boc-1,2-diaminocyclohexane
  • Trans (1R,2R)-1N-Boc-cyclohexane-1,2-diamine
  • Carbamic acid, N-[(1R,2R)-2-aminocyclohexyl]-, 1,1-dimethylethyl ester
  • N-Boc-1R,2R-Cyclohexanediamine
  • ((1R,2R)-2-Aminocyclohexyl)-carbamic acid tert-butyl ester
  • (1R,2R)-(-)-N-(t-Butoxycarbonyl)-1,2-cyclohexanediamine
  • (1R,2R)-N-tert.-Butoxycarbonylcyclohexane-1,2-diamine
CAS:
146504-07-6
MF:
C11H22N2O2
MW:
214.3
Mol File:
146504-07-6.mol
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(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine Chemical Properties

Melting point:
114-115℃
Boiling point:
322.1±31.0 °C(Predicted)
Density 
1.02±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
form 
powder to crystal
pka
12.26±0.40(Predicted)
color 
White to Almost white
optical activity
[α]/D -26±2°, c = 1 in chloroform
BRN 
7023564
InChIKey
AKVIZYGPJIWKOS-RKDXNWHRSA-N
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 3259 8/PG 3
WGK Germany 
3
HazardClass 
8
PackingGroup 
HS Code 
29242990
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(1R,2R)-trans-N-Boc-1,2-Cyclohexanediamine Usage And Synthesis

Chemical Properties

White powder

Uses

(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine can be used as:

  • An organocatalyst in the intramolecular desymmetrization of cyclohexanones to yield 2-azabicyclo[3.3.1]nonane.
  • A starting material in the synthesis of a chiral nickel catalyst applicable for the Michael addition reaction of 1,3-dicarbonyl compounds to yield nitroalkenes.

Definition

ChEBI: (1R,2R)-trans-N-Boc-1,2-cyclohexanediamine is an amine.

(1R,2R)-trans-N-Boc-1,2-CyclohexanediamineSupplier

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