CHLOROTITANIUM TRIISOPROPOXIDE Chemical Properties

Melting point:

35-40 °C

Boiling point:

63-66°C 0,1mm

Density 

1.091 g/mL at 25 °C (lit.)

Flash point:

72 °F

storage temp. 

Flammables area

form 

liquid

Specific Gravity

1.091

color 

fused solid to pale yellow

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

Sensitive 

Moisture Sensitive

BRN 

4163222

CAS DataBase Reference

20717-86-6(CAS DataBase Reference)

EPA Substance Registry System

Titanium, chlorotris(2-propanolato)-, (T-4)- (20717-86-6)

Safety Information

Hazard Codes 

C,F,N

Risk Statements 

10-34-23/24/25-11-67-65-62-51/53-48/20

Safety Statements 

26-36/37/39-45-27-16-62-61

RIDADR 

UN 2924 3/PG 2

WGK Germany 

3

F 

3-10-21

TSCA 

No

HazardClass 

4.1

PackingGroup 

II

HS Code 

29051990

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

CHLOROTITANIUM TRIISOPROPOXIDE Usage And Synthesis

Chemical Properties

Colorless to yellow liquid or low melting solid,

Uses

Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes.

Purification Methods

When distilled under vacuum, the distillate sets slowly to a solid on standing. Stock reagents are made by dissolving the warm liquid in pentane, toluene, Et2O, THF, CH2Cl2,, and can be stored in a pure state or in solution under dry N2 for several months. The reagent is hygroscopic and is hydrolysed by H2O. [Reetz et al. Chem Ber 118 1421 1985.]

CHLOROTITANIUM TRIISOPROPOXIDE(20717-86-6)Related Product Information

• TIN(IV) TERT-BUTOXIDE
• (TERT-BUTYLIMINO)TRIS(DIMETHYLAMINO)TANTALUM
• Tetra-tert-butyl orthotitanate
• Lithium tert-butoxide
• t-Amylimidotris(dimethylamido)tantalum(V) TAIMATA
• TRIETHYLGALLIUM
• TRIETHYLANTIMONY
• Dichloromethane
• TITANIUM HYDRIDE
• TITANIUM
• CHLOROTITANIUM TRIISOPROPOXIDE