CHLOROTITANIUM TRIISOPROPOXIDE
- Product Name
- CHLOROTITANIUM TRIISOPROPOXIDE
- CAS No.
- 20717-86-6
- Chemical Name
- CHLOROTITANIUM TRIISOPROPOXIDE
- Synonyms
- CTT;CHLOROTRIISOPROPOXYTITANIUM;CHLOROTIISOPROPOXYTITANIUM;CHLOROTRIISOPROPYLOXYTITANE;Triisopropoxychlorotitanium;orotriisopropoxytitanium(IV);CHLOROTITANIUM TRIISOPROPOXIDE;CHLOROTITANIUM TRIISOPROPYLATE;Triisopropoxytitanium chloride;Chlorotitanium tri-i-propoxide,
- CBNumber
- CB4141400
- Molecular Formula
- C9H21ClO3Ti
- Formula Weight
- 260.58
- MOL File
- 20717-86-6.mol
CHLOROTITANIUM TRIISOPROPOXIDE Property
- Melting point:
- 35-40 °C
- Boiling point:
- 63-66°C 0,1mm
- Density
- 1.091 g/mL at 25 °C (lit.)
- Flash point:
- 72 °F
- storage temp.
- Flammables area
- solubility
- sol most nonprotic organic solvents, e.g. Et2O, THF, CH2Cl2, toluene, hexanes
- form
- liquid
- color
- fused solid to pale yellow
- Specific Gravity
- 1.091
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Sensitive
- Moisture Sensitive
- BRN
- 4163222
- CAS DataBase Reference
- 20717-86-6(CAS DataBase Reference)
- EPA Substance Registry System
- Titanium, chlorotris(2-propanolato)-, (T-4)- (20717-86-6)
Safety
- Hazard Codes
- C,F,N
- Risk Statements
- 10-34-23/24/25-11-67-65-62-51/53-48/20
- Safety Statements
- 26-36/37/39-45-27-16-62-61
- RIDADR
- UN 2924 3/PG 2
- WGK Germany
- 3
- F
- 3-10-21
- TSCA
- No
- HazardClass
- 4.1
- PackingGroup
- II
- HS Code
- 29051990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H228Flammable solid
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P240Ground/bond container and receiving equipment.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 250627
- Product name
- Chlorotriisopropoxytitanium(IV)
- Purity
- 95%
- Packaging
- 100g
- Price
- $81
- Updated
- 2024/03/01
- Product number
- 250627
- Product name
- Chlorotriisopropoxytitanium(IV)
- Purity
- 95%
- Packaging
- 800g
- Price
- $789
- Updated
- 2023/06/20
- Product number
- 22-0380
- Product name
- Chlorotitanium triisopropoxide, 97%
- Packaging
- 25g
- Price
- $74
- Updated
- 2024/03/01
- Product number
- 22-0380
- Product name
- Chlorotitanium triisopropoxide, 97%
- Packaging
- 100g
- Price
- $224
- Updated
- 2024/03/01
- Product number
- 252670
- Product name
- Chlorotriisopropoxytitanium(IV) solution
- Purity
- 1.0 M in hexanes
- Packaging
- 100ml
- Price
- $75.4
- Updated
- 2024/03/01
CHLOROTITANIUM TRIISOPROPOXIDE Chemical Properties,Usage,Production
Chemical Properties
Colorless to yellow liquid or low melting solid,
Uses
Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes.
Synthesis Reference(s)
1. Reetz, M. T.; Westermann, J.; Steinbach, R.; Wenderoth, B.; Peter, R.; Ostarek, R.; Maus, S. CB 1985, 118, 1421.
Synthesis
Chlorotitanium triisopropoxide can be easily made from a 3:1 mixture of Titanium Tetraisopropoxide and Titanium(IV) Chloride,1 which can be distilled to give the pure reagent or used in situ.
Purification Methods
When distilled under vacuum, the distillate sets slowly to a solid on standing. Stock reagents are made by dissolving the warm liquid in pentane, toluene, Et2O, THF, CH2Cl2,, and can be stored in a pure state or in solution under dry N2 for several months. The reagent is hygroscopic and is hydrolysed by H2O. [Reetz et al. Chem Ber 118 1421 1985.]
Precautions
Chlorotitanium triisopropoxide is corrosive; moisture sensitive; flammable liquid; can be stored under nitrogen, in pure form or in solution, for months.
CHLOROTITANIUM TRIISOPROPOXIDE Preparation Products And Raw materials
Raw materials
Preparation Products
CHLOROTITANIUM TRIISOPROPOXIDE Suppliers
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View Lastest Price from CHLOROTITANIUM TRIISOPROPOXIDE manufacturers
- Product
- CHLOROTITANIUM TRIISOPROPOXIDE 20717-86-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kgs
- Release date
- 2020-01-29