CHLOROTITANIUM TRIISOPROPOXIDE Property

Melting point:

35-40 °C

Boiling point:

63-66°C 0,1mm

Density 

1.091 g/mL at 25 °C (lit.)

Flash point:

72 °F

storage temp. 

Flammables area

form 

liquid

Specific Gravity

1.091

color 

fused solid to pale yellow

Hydrolytic Sensitivity

7: reacts slowly with moisture/water

Sensitive 

Moisture Sensitive

BRN 

4163222

CAS DataBase Reference

20717-86-6(CAS DataBase Reference)

EPA Substance Registry System

Titanium, chlorotris(2-propanolato)-, (T-4)- (20717-86-6)

Safety

Hazard Codes 

C,F,N

Risk Statements 

10-34-23/24/25-11-67-65-62-51/53-48/20

Safety Statements 

26-36/37/39-45-27-16-62-61

RIDADR 

UN 2924 3/PG 2

WGK Germany 

3

F 

3-10-21

TSCA 

No

HazardClass 

4.1

PackingGroup 

II

HS Code 

29051990

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H228Flammable solid

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

CHLOROTITANIUM TRIISOPROPOXIDE Chemical Properties,Usage,Production

Chemical Properties

Colorless to yellow liquid or low melting solid,

Uses

Chlorotriisopropoxytitanium(IV) solution may be used as a precursor for the synthesis of ultralow density ceramic materials. The product may be used to mediate a reductive amination reaction of 5α-cholestane-3,7-dione to yield aryl aminocholestanes.

Purification Methods

When distilled under vacuum, the distillate sets slowly to a solid on standing. Stock reagents are made by dissolving the warm liquid in pentane, toluene, Et2O, THF, CH2Cl2,, and can be stored in a pure state or in solution under dry N2 for several months. The reagent is hygroscopic and is hydrolysed by H2O. [Reetz et al. Chem Ber 118 1421 1985.]