Basic information Reaction Safety Supplier Related

(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl

Basic information Reaction Safety Supplier Related

(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl Basic information

Product Name:
(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl
Synonyms:
  • (S)-(-)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
  • (S)-2-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
  • (S)-(-)-MOP
  • (S)-MOP
  • (S)-(-)-(DIPHENYLPHOSPHINO)-2'-METHOXY-1,1'-BINAPHTHYL
  • (S)-(-)-(DIPHENYLPHOSPHINO)-2''-METHOXY-1,1''-BINAPHTHYL (S)-MOP
  • (S)-(2'-Methoxy[1,1'-binaphthalen]-2-yl)diphenyl-phosphine
  • (S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl
CAS:
134484-36-9
MF:
C33H25OP
MW:
468.52
Product Categories:
  • Chiral Phosphine
  • API intermediates
  • Chiral Reagents
Mol File:
134484-36-9.mol
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(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl Chemical Properties

Melting point:
175-179°C
Boiling point:
584.1±38.0 °C(Predicted)
alpha 
-67° ±2° (c 1, toluene)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
almost transparency in Toluene
form 
Powder
color 
white
Sensitive 
air sensitive
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Safety Information

HS Code 
2931.90.6000
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(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthyl Usage And Synthesis

Reaction

  1. Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols.
  2. Ligand for palladium-catalyzed asymmetric reduction of allylic esters.
  3. Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes.
  4. Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins.

(S)-2-Diphenyphosphino-2'-methoxyl-1,1'-binaphthylSupplier

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