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TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX

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TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX Basic information

Product Name:
TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX
Synonyms:
  • TRICHLOROTRIS(TETRAHYDROFURAN)TITANIUM (III)
  • Titanium(III) chloride tetrahydrofuran complex,97%
  • Trichlorotris(tetrahydrofuran) titanium(Ⅲ)
  • TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX
  • TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX (1:3)
  • TrichlorotristetrahydrofurantitaniumIIImin
  • Trichlorotris(tetrahydrofurane)titanium(III)
  • Trichlorotris(tetrahydrofuran)titanium(III),min.97%
CAS:
18039-90-2
MF:
C12H24Cl3O3Ti
MW:
370.54
Product Categories:
  • Catalysis and Inorganic Chemistry
  • Chemical Synthesis
  • Titanium
  • metal halide
Mol File:
18039-90-2.mol
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TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX Chemical Properties

Melting point:
250 °C
storage temp. 
Refrigerator (+4°C) + Flammables area
form 
Powder or Crystals
color 
Blue to blue-green
Sensitive 
air sensitive, moisture sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
InChI
1S/3C4H8O.3ClH.Ti/c3*1-2-4-5-3-1;;;;/h3*1-4H2;3*1H;/q;;;;;;+3/p-3
InChIKey
MIDYWIPTCYRMQF-UHFFFAOYSA-K
SMILES
Cl[Ti](Cl)Cl.C1CCOC1.C2CCOC2.C3CCOC3
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Safety Information

Hazard Codes 
C-F,C,F
Risk Statements 
34-29-19-14-11
Safety Statements 
8-45-36/37/39-26-16-27
RIDADR 
2925
WGK Germany 
WGK 3
HS Code 
29310099
Storage Class
4.1B - Flammable solid hazardous materials
Hazard Classifications
Flam. Sol. 1
Skin Corr. 1B

MSDS

  • Language:English Provider:ACROS
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TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEX Usage And Synthesis

Chemical Properties

Blue crystalline powder

reaction suitability

reagent type: catalyst
core: titanium

Synthesis

Titanium(III) chloride tetrahydrofuran complex was prepared as follows: to a 2L round-bottomed flask (fitted with a thermometer, mechanical stirrer and reflux condenser) was added granulated titanium (~100 mesh, 99.9 purity, 8.3 g), titanium tetrachloride (98.6 g) and toluene (800 g). THF (432 g) was added under ice cooling while maintaining the tank temperature at 10-20 ??C. The reaction mixture was heated to reflux (90-100 ??C) for 6 hours. The reaction mixture was then cooled to room temperature and filtered. The solid tetrahydrofuran titanium chloride product was washed with deoxyhexane (200 mL) and dried under vacuum, yield = 240 g; 94%, based on the total charge of titanium (TiCl4 and particulate titanium).

TITANIUM(III) CHLORIDE TETRAHYDROFURAN COMPLEXSupplier

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