ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic ruthenium > RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Basic information
- Product Name:
- RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)
- Synonyms:
-
- BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)RUTHENIUM(II)
- BIS-(2-METHYLALLYL)CYCLOOCTA-1,5-DIENE RUTHENIUM (II) COMPLEX
- BIS(2-METHYLALLYL) (1,5-CYCLOOCTADIENE)&
- BIS(2-METHYLALLYL)(1,5-CYCLOOCTADIENE)R&
- RutheniumCyclooctadieneBis(2,2,6,6-Tetramethylheptanedionate)
- bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(ii),min.
- Bis-(2-methylallyl)cycloocta-1,5-diene ruthenium(II) complex, 30-32% Ru
- Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II),min.97%
- CAS:
- 12289-94-0
- MF:
- C16H18Ru
- MW:
- 311.39
- Product Categories:
-
- organometallic complex
- Ru
- Mol File:
- 12289-94-0.mol
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Chemical Properties
- Melting point:
- 81-85 °C
- Boiling point:
- 100°C/0.05mmHg
- storage temp.
- -20°C
- form
- Powder
- color
- tan to brown
- Water Solubility
- It is soluble in water.
- Sensitive
- Air & Moisture Sensitive
- Stability:
- store cold
- InChIKey
- KMYRLYRRLMVJNK-XMWBDPRZSA-N
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Safety Information
- Hazard Codes
- Xn,F
- Risk Statements
- 20/21/22-15
- Safety Statements
- 36/37-43
- RIDADR
- UN3395
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 4.3
- PackingGroup
- III
- HS Code
- 28439000
MSDS
- Language:English Provider:ACROS
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RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE) Usage And Synthesis
Reaction
- Convenient precatalyst for Ru-catalyzed asymmetric hydrogenations (L2RuBr2 prepared in situ).
- β-ketoester reduction.
- Anti-Markovnikov addition of amides to alkynes.
- Anti-Markovnikov hydroamination of vinylarenes.
- Catalyst for the addition of amides to alkynes.
Chemical Properties
tan/brown powder
Uses
Bis(2-methylallyl)(1,5-cyclooctadiene)ruthenium(II) is used as a catalyst and pharmaceutical intermediate. It is also used as a precatalysts for asymmetric and Cross-Coupling Catalysis reactions, and in organic chemical synthesis.
Uses
Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
General Description
This product has been enhanced for catalytic efficiency.
RUTHENIUM II CYCLOOCTADIENE BIS-(2,2,6,6-TETRAMETHYLHEPTANEDIONATE)Supplier
Shanghai Incat Chemtech Co.,Ltd. Gold
- Tel
- 021-57603038 13601791340
- 307593986@qq.com
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006608290; 18621169109
- market03@meryer.com
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com