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Butyltriphenylphosphonium chloride

Basic information Application Safety Supplier Related

Butyltriphenylphosphonium chloride Basic information

Product Name:
Butyltriphenylphosphonium chloride
Synonyms:
  • BTC
  • BUTYLTRIPHENYLPHOSPHONIUM CHLORIDE
  • TRIPHENYLBUTYLPHOSPHONIUM CHLORIDE
  • butyltriphenyl-phosphoniuchloride
  • BUTYLTRIPHENYL PHOSPHONIUM CHLORIDE 98%
  • (1-Butyl)triphenylphosphonium chloride
  • butyl(triphenyl)phosphanium
  • Phosphonium, butyltriphenyl-, chloride
CAS:
13371-17-0
MF:
C22H24ClP
MW:
354.85
EINECS:
236-443-3
Product Categories:
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents
Mol File:
13371-17-0.mol
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Butyltriphenylphosphonium chloride Chemical Properties

Melting point:
226-230 °C(lit.)
Flash point:
>270°C
storage temp. 
Store below +30°C.
solubility 
soluble in Methanol
form 
solid
color 
White to Light yellow
optical activity
233.2-237.8℃°
Water Solubility 
soluble
Sensitive 
Hygroscopic
CAS DataBase Reference
13371-17-0(CAS DataBase Reference)
EPA Substance Registry System
Phosphonium, butyltriphenyl-, chloride (13371-17-0)
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Safety Information

Hazard Codes 
Xi,Xn
Risk Statements 
36/37/38-22
Safety Statements 
26-36-37/39
WGK Germany 
3
TSCA 
Yes
HS Code 
2931 39 90
HazardClass 
6.1
Toxicity
LD50 orally in Rabbit: 320 mg/kg

MSDS

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Butyltriphenylphosphonium chloride Usage And Synthesis

Application

Butyltriphenylphosphine chloride is a quaternary phosphonium salt containing a monoalkyltriphenyl substituent. The phosphorus atom possesses three unpaired electrons, one lone pair of electrons, and five empty 3d orbitals, giving Ph3P+ electron-withdrawing properties. This also allows the quaternary phosphonium salt cation to bind well with F-, which is beneficial for fluorination reactions. Due to its good catalytic effect, high selectivity, high thermal stability, low toxicity, and recyclability, quaternary phosphonium salt phase transfer catalysts have been widely used in recent years.

Chemical Properties

white to off-white crystalline powder

Butyltriphenylphosphonium chlorideSupplier

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