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[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE

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[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Basic information

Product Name:
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE
Synonyms:
  • [2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE
  • ETHYL (TRIPHENYLPHOSPHORANYLIDENE)PYRUVATE
  • Ethyl (triphenylphosphoranylidene)pyruvate, [2-(Ethoxycarbonyl)-2-oxoethylidene]triphenylphosphorane
  • Ethyl 2-oxo-3-(triphenylphosphoranylidene)propanoate
  • [(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester
  • NSC 647346
  • Ethyl (triphenylphosphoranylidene)pyruvate 95%
  • [2-(Ethoxycarbonyl)-2-oxoethylidene]triphenylphosphorane , 95 % min.
CAS:
13321-61-4
MF:
C23H21O3P
MW:
376.38
Product Categories:
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents
Mol File:
13321-61-4.mol
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[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Chemical Properties

Melting point:
175 °C (dec.) (lit.)
Boiling point:
524.6±33.0 °C(Predicted)
Density 
1.20±0.1 g/cm3(Predicted)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
HS Code 
29310099

MSDS

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[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Usage And Synthesis

Chemical Properties

off-white to yellow or brown powder

Uses

Reactant for:

  • Wittig condensation
  • Chemoenzymic preparation of hexafluoroleucine and tetrafluoroleucine

Reactant for synthesis of:
  • Ahiral and chiral cyclic dehydro-α-amino acid derivatives through nucleophilic addition
  • Peptidyl α-keto-based inhibitors of cruzain
  • Deoxyfluoro-L-arabinofuranosyl triazole nucleoside derivatives with antiviral activity
  • Anti-human immunodificiency virus analogs

[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANESupplier

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