Basic information Safety Supplier Related

(S)-(-)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL

Basic information Safety Supplier Related

(S)-(-)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL Basic information

Product Name:
(S)-(-)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL
Synonyms:
  • (S)-(-)-1-(1-NAPHTHYL)ETHANOL
  • (S)-1-NAPHTHALEN-1-YL-ETHANOL
  • (S)-(-)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL
  • (s)-(-)-α-methyl-1-naphthalenemethanol
  • s-(-)-α-methyl-1-naphthalenemethanol
  • S-(-)-1-(1-NAPTHALENYL)ETHANOL
  • (S)-1-Naphthylethanol
  • (1S)-1-(1-Naphthyl)ethanol
CAS:
15914-84-8
MF:
C12H12O
MW:
172.22
EINECS:
1592732-453-0
Product Categories:
  • Alcohols, Hydroxy Esters and Derivatives
  • Chiral Compounds
Mol File:
15914-84-8.mol
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(S)-(-)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL Chemical Properties

Melting point:
47-49 °C(lit.)
alpha 
-77 º (C=1 IN MEOH)
Boiling point:
165°C/11mmHg(lit.)
Density 
1.113±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
14.29±0.20(Predicted)
form 
Powder
color 
Yellow
optical activity
[α]20/D 77°, c = 1 in methanol
BRN 
2045009
InChI
InChI=1/C12H12O/c1-9(13)11-8-4-6-10-5-2-3-7-12(10)11/h2-9,13H,1H3/t9-/s3
InChIKey
CDRQOYRPWJULJN-DJEYLCQNNA-N
SMILES
C12C=CC=CC=1C=CC=C2[C@@H](O)C |&1:10,r|
CAS DataBase Reference
15914-84-8(CAS DataBase Reference)
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Safety Information

Risk Statements 
22-24/25
Safety Statements 
22-24/25
WGK Germany 
3
HS Code 
29062990

MSDS

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(S)-(-)-ALPHA-METHYL-1-NAPHTHALENEMETHANOL Usage And Synthesis

Chemical Properties

White fine crystalline powder

Uses

(S)?-?1-?(Naphthalen-?1-?yl)?ethanol is a building block used in the synthesis of novel 2,4-diaminoquinazoline derivatives as SMN2 promoter activators for the potential treatment of spinal muscular atrophy.

Purification Methods

Purify the alcohol by recrystallisation from Et2O/pet ether, Et2O, hexane [Balfe et al. J Chem Soc 797 1946, IR, NMR: Theisen & Heathcock J Org Chem 53 2374 1988, see also Fredga et al. Acta Chem Scand 11 1609 1957]. The RS-alcohol [57605-95-5] has m 63-65o, 65-66o from hexane. [Beilstein 6 III 3034, 6 IV 4346.]

(S)-(-)-ALPHA-METHYL-1-NAPHTHALENEMETHANOLSupplier

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