1-(3-Bromophenyl)-1H-pyrrole Chemical Properties

Melting point:

63 °C

Boiling point:

294.9±23.0 °C(Predicted)

Density 

1.38±0.1 g/cm3(Predicted)

storage temp. 

Sealed in dry,Room Temperature

pka

-5.74±0.70(Predicted)

CAS DataBase Reference

107302-22-7(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38-41-37/38

Safety Statements 

26-37/39-39

Hazard Note 

Irittant

HazardClass 

IRRITANT

HS Code 

2933998090

1-(3-Bromophenyl)-1H-pyrrole Usage And Synthesis

Synthesis

General procedure: m-Bromoaniline (1 mmol), 2,5-dimethoxytetrahydrofuran (1.1 mmol) and L-(+)-tartaric acid-chlorocholinesterase DES (1.5 g) were added to a 50 mL round-bottomed flask and the reaction mixture was stirred at 90°C. The reaction was carried out by thin-layer chromatography (TLC). The reaction process was monitored by thin layer chromatography (TLC). After completion of the reaction, the mixture was cooled to room temperature and the target product 1-(3-bromophenyl)-1H-pyrrole was extracted with ethyl acetate. After evaporation of the solvent, the residue was purified by silica gel column chromatography to give the pure product.DES was dried under vacuum and reused for the next cycle.

References

[1] Asian Journal of Chemistry, 2013, vol. 25, # 1, p. 501 - 504
[2] Journal of Molecular Liquids, 2014, vol. 198, p. 259 - 262,4
[3] Applied Catalysis A: General, 2013, vol. 457, p. 34 - 41
[4] Journal of the Chemical Society. Perkin Transactions 1, 2001, # 9, p. 1039 - 1043
[5] Journal of Heterocyclic Chemistry, 2000, vol. 37, # 1, p. 15 - 24

1-(3-Bromophenyl)-1H-pyrrole(107302-22-7)Related Product Information

• N-Methyl-2-pyrrolidone
• N-Vinyl-2-pyrrolidone
• Pyrrole
• Polyvinylpyrrolidone
• Povidone iodine
• Propiophenone
• METHYL-2-PYRROLIDONE
• 1-(2-BROMOPHENYL)-1H-PYRROLE
• 1-(2-BROMOPHENYL)-1H-PYRROLE-2,5-DIONE
• 1-(4-BROMOPHENYL)-1H-PYRROLE-2,5-DIONE
• 2,5-Dimethyl-1-(4-bromophenyl)-1H-pyrrole
• ASISCHEM V95407
• 1-(3-BROMOPHENYL)-2,5-DIMETHYL-1H-PYRROLE-3-CARBALDEHYDE
• 1-(3-BROMOPHENYL)-1H-PYRROLE-2-CARBALDEHYDE
• 2-BROMO-5-(2',5'-DIMETHYL) PYRROLIDYL PYRIDINE
• 1-(3-BROMOPHENYL)-2,5-DIMETHYL-1H-PYRROLE-3-METHANOL
• 1-(3-BROMOPHENYL)-2,5-DIMETHYL-1H-PYRROLE-3-CARBOXYLIC ACID
• 4-(4-BROMOPHENYL)-1H-PYRROLE-3-CARBOXYLIC ACIDETHYL ESTER