TETRAPROPYLAMMONIUM PERRUTHENATE
TETRAPROPYLAMMONIUM PERRUTHENATE Basic information
- Product Name:
- TETRAPROPYLAMMONIUM PERRUTHENATE
- Synonyms:
-
- TETRAPROPYLAMMONIUM PERRUTHENATE
- TETRA-N-PROPYLAMMONIUM PERRUTHENATE
- TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
- TPAP
- Tetrapropylammonium tetraoxoruthenate
- TerapropylaMMoniuMperruthenate
- TetrapropylaMMoniuM perruthenate,97% TPAP, (n-C3H7)4NRuO4
- 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoru
- CAS:
- 114615-82-6
- MF:
- C12H28NO4Ru
- MW:
- 351.43
- EINECS:
- 628-415-8
- Product Categories:
-
- Boron, Nitrile, Thio,& TM-Cpds
- Ammonium Polyhalides, etc. (Quaternary)
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Environmentally-friendly Oxidation
- Homogeneous Catalysts
- Metal Complexes
- Oxidation
- Quaternary Ammonium Compounds
- Ru (Ruthenium) Compounds
- Synthetic Organic Chemistry
- Transition Metal Complexes (Environmentally-friendly Oxidation)
- Transition Metal Compounds
- Ru
- Alkylammonium salt
- Mol File:
- 114615-82-6.mol
TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties
- Melting point:
- ~160 °C (dec.) (lit.)
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Methanol (Slightly)
- form
- crystal
- color
- green
- Water Solubility
- Insoluble in water.
- Sensitive
- Hygroscopic
- Stability:
- store cold
- InChIKey
- NQSIKKSFBQCBSI-UHFFFAOYSA-N
Safety Information
- Hazard Codes
- O,Xi
- Risk Statements
- 5-8-36/37/38
- Safety Statements
- 17-26-36
- RIDADR
- UN 1479 5.1/PG 2
- WGK Germany
- 3
- F
- 3-10
- HazardClass
- 5.1
- PackingGroup
- III
- HS Code
- 28439000
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
TETRAPROPYLAMMONIUM PERRUTHENATE Usage And Synthesis
Uses
A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.
Chemical Properties
dark green solid
Uses
Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.
Definition
ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.
General Description
Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
Purification Methods
It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially.
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