Tritosulfuron Chemical Properties

Density 

1.639±0.06 g/cm3(Predicted)

Flash point:

>204 °C

solubility 

Solubility in organic solvents (g/l at 20 °C)
Acetone -
Acetonitrile -
Ethyl acetate 83.0
Dichloromethane 25.0
n‐Heptane <0.001
Methanol 23
Toluene 4.2

pka

Dissociation constant (pKa at 20 °C) 4.69

Water Solubility 

Solubility in water (g/l at 20 °C)
<0.001 (pH 1.7)
0.04 (pH 7.0)
78.32 (pH 10.2)

LogP

4.480 (est)

Safety Information

Hazard Codes 

Xi,N

Risk Statements 

43-51/53

Safety Statements 

36/37-61

RIDADR 

UN3077 9/PG 3

WGK Germany 

2

Tritosulfuron Usage And Synthesis

Uses

Tritosulfuron is a sulfonylurea herbicide found in in ground, surface and wastewater.

Definition

ChEBI: A sulfonamide that is benzenesulfonamide substituted by a trifluoromethyl group at position 2 and a [4-methoxy-6-(trifluoromethyl)-1,3,5-triazin-2-yl]carbamoyl group at the nitrogen atom.

Agricultural Uses

Tritosulfuron (BAS-635) is a broad-spectrum post-emergent dicotyledonous herbicide mainly for use in cereals, rice, maize, and turf with application rates of 40–75 g a.i. ha−1. In cereals, it was commercialized by BASF in 2004 under the trade name “Biathlon®” as a water-dispersible (WG) formulation containing 714 g kg−1 tritosulfuron and is applied at a rate of 50 g a.i. ha−1. The following weeds are well controlled: T. arvense, Mercurialis annua, Urticaurens, C. arvense, Veronica hederifolia, Chenopodium spp., S. arvensis, C. bursapastoris, G. tetrahit, Matricaria spp., G. aparine, Polygonum spp., C. cyanus, Lamium spp., M. arvensis, S. media, Vicia spp., Convolvulus arvensis, Sonchus arvensis, and B. napus. Tritosulfuron acts mainly through the treated leaves, and not via the soil. The compound has the advantage of having a short soil half-life (DT50), which allows recropping after 60 days without plowing.
Tritosulfuron is selective in the following cereal crops: wheat, rye, barley, triticale, oat, durum wheat, and spelt. The application window of tritosulfuron in all winter and summer cereals ranges from vegetation start up to growth stage (GS) 39. Sold in maize as “Tooler®,” it can be applied from GS 12 to GS 18.

Tritosulfuron(142469-14-5)Related Product Information

• Trifloxysulfuron
• Sulfometuron-methyl
• Acetaldoxime
• DITHIANON
• CHROMOTROPE 2R
• 2-AMINO-4-METHOXY-6-METHYL-1,3,5-TRIAZINE
• Tritosulfuron
• 4-Methoxy-N,6-dimethyl-1,3,5-triazin-2-amine