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TRI(2-FURYL)PHOSPHINE

Basic information Reaction Safety Supplier Related

TRI(2-FURYL)PHOSPHINE Basic information

Product Name:
TRI(2-FURYL)PHOSPHINE
Synonyms:
  • SALOR-INT L308749-1EA
  • TRIS(2-FURYL)PHOSPHINE
  • TRI(2-FURYL)PHOSPHINE
  • Tri(2-furyl)phospine
  • Tri(2-furyl)phosphine,97%
  • Tri(2-furyL
  • TFP / Tri(2-furyl)phosphine
  • Tri(fur-2-yl)phosphine
CAS:
5518-52-5
MF:
C12H9O3P
MW:
232.17
EINECS:
628-036-8
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • organophosphorus ligand
  • Aromatics
  • Chelating Agents & Ligands
  • Heterocycles
  • Ligand
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphine Ligands
  • Phosphorus Compounds
Mol File:
5518-52-5.mol
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TRI(2-FURYL)PHOSPHINE Chemical Properties

Melting point:
59-64 °C (lit.)
Boiling point:
136 °C/4 mmHg (lit.)
Flash point:
136°C/4mm
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
solid
color 
faintly brown
Sensitive 
air sensitive
BRN 
1577564
InChI
InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChIKey
DLQYXUGCCKQSRJ-UHFFFAOYSA-N
SMILES
P(C1=CC=CO1)(C1=CC=CO1)C1=CC=CO1
CAS DataBase Reference
5518-52-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-24/25
WGK Germany 
3
10-23
TSCA 
No
HS Code 
29319090

MSDS

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TRI(2-FURYL)PHOSPHINE Usage And Synthesis

Reaction

  1. Useful ligand for C-C coupling reactions.
  2. Ligand used for the alkynylation of thioesters.
  3. Ligand used for enol ester formation.
  4. Ligand for palladium-catalyzed 3-Component coupling.
  5. Ligand for palladium-catalyzed C-C coupling reaction.
  6. Ligand for trans-olefin formation.
  7. Olefin formation from N-tosylhydrazones and benzyl halides.
  8. C-H arylation/alkenylation of 1-substituted tetrazoles. 

Chemical Properties

TRI(2-FURYL)PHOSPHINE is white to light yellow crystal powde

Uses

TRI(2-FURYL)PHOSPHINE is a phopshine ligand used in transition-metal mediated organic synthesis, in particular in wittig reactions to improved (Z) selectivity.

Uses

suzuki reaction

TRI(2-FURYL)PHOSPHINESupplier

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