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TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE

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TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Basic information

Product Name:
TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
Synonyms:
  • Tetrakis(acetonitrile)palladium(II)tetrafluoroborate,99%
  • TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE
  • TETRAKIS(ACETONITRILE)PALLADIUM(II) BIS(TETRAFLUOROBORATE)
  • PALLADIUM(II) TETRAFLUOROBORATE-TETRAACETONITRILE COMPLEX
  • TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE (30%PD)
  • Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, Pd 23.9%
  • Tetrakis(acetonitrile)palladiuM(II) tetrafluoroborate, 99% 1GR
  • NSC 307191
CAS:
21797-13-7
MF:
C8H12BF4N4Pd+
MW:
357.44
Product Categories:
  • Pd
  • organometallic complex
Mol File:
21797-13-7.mol
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TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Chemical Properties

Melting point:
230 °C (dec.) (lit.)
storage temp. 
Inert atmosphere,2-8°C
form 
Powder
color 
Yellow
Water Solubility 
Soluble in water
Sensitive 
Air Sensitive
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20
Safety Statements 
22-36/37/39-38
RIDADR 
UN2811
WGK Germany 
3
HazardClass 
6.1
PackingGroup 
III
HS Code 
29310099

MSDS

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TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE Usage And Synthesis

Chemical Properties

Yellow powder

Uses

Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation.

Uses

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Reactant involved in:

  • Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands

Precursor for:
  • Synthesis of dendritic SCS-pincer palladium complexes
  • Palladium complexes of click ligands
  • Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination

General Description

Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction.

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