Basic information Reactions Safety Supplier Related

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

Basic information Reactions Safety Supplier Related

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Basic information

Product Name:
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms:
  • 3,4-a']dinaphthalen-4-yl)morpholine,min.97%(S)-MorfPhos
  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine, min. 97% (S)-MorfPhos
  • 97% (S)-MorfPhos
  • (S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-yl)morpholine
  • 4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine
  • 4-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin- 4-ylmorpholine,99%e.e.
  • 3,4-a']dinaphthalen-4-yl)Morpholine (S)-MorfPhos
  • (S)-MorfPhos
CAS:
185449-81-4
MF:
C24H20NO3P
MW:
401.39
Product Categories:
  • Chiral Phosphine
  • CPN
Mol File:
185449-81-4.mol
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties

Boiling point:
613.7±65.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
-0.88±0.20(Predicted)
form 
Powder
color 
white
Sensitive 
moisture sensitive
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(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Usage And Synthesis

Reactions

1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
2. Ligand used in iridinium-catalyzed asymmetric hydrogenation of 2-methylindole.

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-aSupplier

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