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METHYLPHOSPHONOTHIOIC DICHLORIDE

Basic information Safety Supplier Related

METHYLPHOSPHONOTHIOIC DICHLORIDE Basic information

Product Name:
METHYLPHOSPHONOTHIOIC DICHLORIDE
Synonyms:
  • P,P-DICHLOROMETHYLPHOSPHINE SULFIDE
  • Dichloro(methylthio)phosphine
  • ethanephosphonothioic dichloride
  • ethyldichlorophosphine sulfide
  • ethylphosphonothioyl dichloride
  • ethylthionophosphonic dichloride
  • ethylthiophosphonic acid dichloride
  • ichloromethylphosphine sulfide
CAS:
676-98-2
MF:
CH3Cl2PS
MW:
148.98
EINECS:
211-636-5
Mol File:
676-98-2.mol
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METHYLPHOSPHONOTHIOIC DICHLORIDE Chemical Properties

Melting point:
-25.5°C
Boiling point:
154-155°C
Density 
1.422 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.548(lit.)
Flash point:
73 °C
form 
liquid
EPA Substance Registry System
Phosphonothioic dichloride, methyl- (676-98-2)
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Safety Information

Hazard Codes 
C
Risk Statements 
14-34
Safety Statements 
26-27-36/37/39-45
RIDADR 
1760
HazardClass 
8
PackingGroup 
II

MSDS

  • Language:English Provider:ALFA
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METHYLPHOSPHONOTHIOIC DICHLORIDE Usage And Synthesis

General Description

A colorless liquid with a pungent odor. Noncombustible. Toxic by inhalation. Denser than water. Corrosive to metal and tissue.

Air & Water Reactions

Reacts with water to form hydrochloric acid, reaction may be violent.

Reactivity Profile

METHYL PHOSPHONOTHIOIC DICHLORIDE is water reactive. Incompatible with strong oxidizing agents, alcohols, bases( including amines). May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

Inhalation causes irritation of nose and throat; effects are quite similar to those of phosgene. Ingestion causes irritation of mouth and stomach. Delayed, painful eye irritation may occur from exposure to vapor; liquid causes severe irritation. Contact with skin causes irritation and burns.

Fire Hazard

Special Hazards of Combustion Products: Irritating hydrogen chloride, sulfur dioxide and other fumes may be formed in fire.

Safety Profile

A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits very toxic fumes of Cl-, POx, and SOx.

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