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SILVER PERCHLORATE HYDRATE

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SILVER PERCHLORATE HYDRATE Basic information

Product Name:
SILVER PERCHLORATE HYDRATE
Synonyms:
  • SILVER PERCHLORATE
  • SILVER PERCHLORATE HYDRATE
  • SILVER PERCHLORATE, HYDRATED
  • SILVER PERCHLORATE MONOHYDRATE
  • SILVER(I) PERCHLORATE HYDRATE
  • SILVER(I) PERCHLORATE MONOHYDRATE
  • SILVER PERCHLORATE MONOHYDRATE, 99.999%
  • SILVER PERCHLORATE, HYDRATED 99.999%
CAS:
14242-05-8
MF:
AgClH3O5
MW:
226.34
EINECS:
677-705-0
Product Categories:
  • metal perchlorate salt
  • Oxidation
  • PerchloratesMetal and Ceramic Science
  • Salts
  • Silver Salts
  • Synthetic Reagents
Mol File:
14242-05-8.mol
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SILVER PERCHLORATE HYDRATE Chemical Properties

Melting point:
43 °C
Density 
2,8 g/cm3
storage temp. 
Refrigerator (+4°C)
form 
Crystals or Crystalline Powder
color 
White
Water Solubility 
Soluble in water and organic solvents.
Sensitive 
Light Sensitive & Hygroscopic
Merck 
14,8523
Stability:
hygroscopic
CAS DataBase Reference
14242-05-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
O,C
Risk Statements 
8-34-1
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1481 5.1/PG 2
WGK Germany 
3
3-8-10
TSCA 
Yes
HazardClass 
5.1
PackingGroup 
II
HS Code 
28432900

MSDS

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SILVER PERCHLORATE HYDRATE Usage And Synthesis

Chemical Properties

WHITE CRYSTALS OR CRYSTALLINE POWDER

Uses

Silver perchlorate can be used in the manufacturing of explosives. It is generally used as a source of silver ions during silver nanoparticles synthesis. It is used as a catalyst in organic chemistry.

Uses

Silver Perchlorate Hydrate is used in the hydroxylation of hexabromotetrahydronaphthalene.

Purification Methods

Reflux it with *benzene (6mL/g) in a flask fitted with a Dean and Stark trap until all the water is removed azeotropically (ca 4hours). The solution is cooled and diluted with dry pentane (4mL/g of AgClO4). The precipitated AgClO4 is filtered off and dried in a desiccator over P2O5 at 1mm for 24hours [Radell et al. J Am Chem Soc 83 3958 1961]. It has also been recrystallised from perchloric acid. [Caution due to its EXPLOSIVE nature in the presence of organic matter.] Store it in the dark.

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