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ChemicalBook >  Product Catalog >  Organic Chemistry >  Organometallic compounds >  Organic iron >  (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS

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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Basic information

Product Name:
(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
Synonyms:
  • (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-
    diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
  • (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl](N,N-diMethylaMino)(2-diphenylphosphinophenyl)Methane
  • 97% TANIAPHOS
  • (S)-1-Diphenylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(diphenylphosphinophenyl)-methyl]ferrocene
  • (S)-(-)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-diMethylaMino) (2-diphenylphosphinophenyl)Methane TANIAPHOS
  • (SP)-1-[(S)-alpha-(DiMethylaMino)-2-(diphenylphosphino)benzyl]-2-diphenylphosphinoferrocene >=97%, optical purity ee: >=99%
  • Taniaphos SL-T001-2, (2R)-1-[(S)-(Dimethylamino)[2-(diphenylphosphino)phenyl]methyl]-2-(diphenylphosphino)ferrocene (acc to CAS)
  • (S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS
CAS:
850444-36-9
MF:
C38H34NP2.C5H5.Fe
MW:
687.581
Product Categories:
  • Chiral Phosphine
  • Ferrocene Series
  • metallocene
  • Taniaphos Series
Mol File:
850444-36-9.mol
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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Chemical Properties

alpha 
-312° ±15° (c 0.5, CHCl3)
storage temp. 
2-8°C
form 
Powder
color 
orange
Stability:
store cold
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Safety Information

WGK Germany 
3
HS Code 
29319090
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(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOS Usage And Synthesis

Reactions

  1. Ligand for the Ru-catalyzed hydrogenation of $-ketoesters, enamides and itaconates.
  2. Ligand for Cu-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic enones.
  3. AgOAc-catalyzed asymmetric amination of glycine Schiff bases with azodicarboxylates. 

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(S)-(+)-[(S)-2-Diphenylphosphinoferrocenyl] (N,N-dimethylamino) (2-diphenylphosphinophenyl)methane, min. 97% TANIAPHOSSupplier

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