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4,4'-DICHLORODIPHENYL DISULFIDE

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4,4'-DICHLORODIPHENYL DISULFIDE Basic information

Product Name:
4,4'-DICHLORODIPHENYL DISULFIDE
Synonyms:
  • 4-Chlorophenyl disulfide
  • DDDS
  • Ddds (pesticide)
  • ddds[pesticide]
  • Disulfide, bis(p-chlorophenyl)
  • disulfide,bis(4-chlorophenyl)
  • disulfide,bis(p-chlorophenyl)
  • Nsc 32025
CAS:
1142-19-4
MF:
C12H8Cl2S2
MW:
287.23
EINECS:
214-531-2
Product Categories:
  • Aromatics
Mol File:
1142-19-4.mol
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4,4'-DICHLORODIPHENYL DISULFIDE Chemical Properties

Melting point:
71-74 °C(lit.)
Boiling point:
180 °C / 2mmHg
Density 
1.304 g/cm3(Temp: 102.3 °C)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Methanol
form 
Solid
color 
Light Yellow
BRN 
1644663
InChIKey
ZIXXRXGPBFMPFD-UHFFFAOYSA-N
CAS DataBase Reference
1142-19-4(CAS DataBase Reference)
EPA Substance Registry System
Disulfide, bis(4-chlorophenyl) (1142-19-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-24/25
WGK Germany 
3
RTECS 
JO0766000
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29309090
Hazardous Substances Data
1142-19-4(Hazardous Substances Data)
Toxicity
mouse,LD50,oral,> 3gm/kg (3000mg/kg),"Pesticide Index," Frear, E.H., ed., State College, PA, College Science Pub., 1969Vol. 4, Pg. 65, 1969.

MSDS

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4,4'-DICHLORODIPHENYL DISULFIDE Usage And Synthesis

Chemical Properties

Light Yellow Solid

Uses

Bis(4-chlorophenyl) disulfide may be used to synthesize non-symmetrical heterodimer 4-chlorophenyl-2′-nitrophenyl disulfide.

Synthesis Reference(s)

Synthetic Communications, 10, p. 305, 1980 DOI: 10.1080/00397918008062754

General Description

Bis(4-chlorophenyl) disulphide can be synthesized from 4-chlorophenylthiol via oxidation. It produces poly(p-phenylene sulfide), via thermolysis. Bis(4-chlorophenyl) disulfide can also be prepared by a microwave assisted method involving the reaction between respective elemental sulfur and 1-chloro-4-iodobenzene in the presence of CuO nanopowder (catalyst).

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