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Sodium hypophosphite

Basic information Safety Supplier Related

Sodium hypophosphite Basic information

Product Name:
Sodium hypophosphite
Synonyms:
  • Phosphinicacid,sodiumsalt
  • phosphinicacidmonosodiumsalt
  • sodiumhydrogenphosphite(nah2po2)
  • sodiumhydrophosphite
  • sodiummonophosphate
  • sodiumphosphinate
  • sodiumphosphinate(nah2po2)
  • Sodium hypophosphite Vetec(TM) reagent grade, 98%
CAS:
7681-53-0
MF:
H2NaO2P
MW:
87.98
EINECS:
231-669-9
Product Categories:
  • Inorganic Salts
  • Synthetic Reagents
  • Inorganic Chemicals
  • Inorganics
  • 7681-53-0
Mol File:
7681-53-0.mol
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Sodium hypophosphite Chemical Properties

Density 
1.77 g/cm3 at 20 °C
color 
white crystals, crystalline
Water Solubility 
909g/L at 30℃
Merck 
13,8703
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
ZGKNDXOLMOFEJH-UHFFFAOYSA-M
CAS DataBase Reference
7681-53-0(CAS DataBase Reference)
EPA Substance Registry System
Sodium hypophosphite (7681-53-0)
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Safety Information

Safety Statements 
17
WGK Germany 
2
RTECS 
WB5950000
Hazardous Substances Data
7681-53-0(Hazardous Substances Data)

MSDS

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Sodium hypophosphite Usage And Synthesis

Chemical Properties

white crystalline powder or colourless crystals

Uses

Pharmaceuticals, reducing agent in electrode- less nickel plating of plastics and metals, lab reagent, substitute for sodium nitrite in smoked meats.

Reactions

Sodium hypophosphite, NaH2PO2 · H2O, white solid, soluble, formed (1) by reaction of hypophosphorous acid and sodium carbonate solution, and then evaporating, (2) by reaction of NaOH solution and phosphorus on heating (poisonous phosphine gas evolved).

Hazard

Explosion risk when mixed with strong oxi- dizing agents, decomposes to phosphine on heating, store in cool, dry place, away from oxidizing mate- rials.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by subcutaneous route. Moderately toxic by intraperitoneal route. Flammable when exposed to heat or flame. Aqueous solutions may explode on evaporation. Potentially explosive reaction with oxidants (e.g., chlorates, nitrates). Heat causes it to evolve phosphne. It can explode. When heated to decomposition it emits toxic fumes of POx and Na2O. See also PHOSPHINE

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