ChemicalBook > Product Catalog > Organic Chemistry > Organometallic compounds > Organic aluminum > ALUMINUM TERT-BUTOXIDE
ALUMINUM TERT-BUTOXIDE
ALUMINUM TERT-BUTOXIDE Basic information
- Product Name:
- ALUMINUM TERT-BUTOXIDE
- Synonyms:
-
- aluminium tri-tert-butanolate
- 2-Propanol, 2-methyl-, aluminum salt
- tri-tert-butoxyaluminum
- Aluminum tert-butoxide, tech. 90%
- Alumiuniumt-butoxide,
- ALUMINUM(III) TERT-BUTOXIDE
- ALUMINUM TRI(tert-BUTOXIDE) TECHNICAL
- Aluminium tert-butoxide, tech. 90%
- CAS:
- 556-91-2
- MF:
- C12H27AlO3
- MW:
- 246.32
- EINECS:
- 209-146-1
- Product Categories:
-
- Al (Alminum) Compounds
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Homogeneous Catalysts
- Synthetic Organic Chemistry
- Titanium Alkoxides, etc. (Homogeneous Catalysts)
- Typical Metal Compounds
- Mol File:
- 556-91-2.mol
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ALUMINUM TERT-BUTOXIDE Chemical Properties
- Melting point:
- 241°C
- Boiling point:
- 156°C 2mm
- Density
- 1,0251 g/cm3
- Flash point:
- >65°C
- solubility
- Very soluble in organic solvents like alcohols, benzene, toluene and xylene.
- form
- Powder
- color
- White to Gray
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Sensitive
- Moisture Sensitive
- Merck
- 14,333
- BRN
- 4148229
- Stability:
- Stable, but air and moisture sensitive. Incompatible with acids, strong oxidizing agents. Highly flammable.
- CAS DataBase Reference
- 556-91-2(CAS DataBase Reference)
- EPA Substance Registry System
- 2-Propanol, 2-methyl-, aluminum salt (556-91-2)
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Safety Information
- Hazard Codes
- F,C
- Risk Statements
- 11-34
- Safety Statements
- 8-16-26-36/37/39-45
- RIDADR
- UN 2925 4.1/PG 2
- WGK Germany
- 3
- F
- 8-21
- TSCA
- Yes
- HazardClass
- 4.1
- PackingGroup
- III
- HS Code
- 29051990
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
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ALUMINUM TERT-BUTOXIDE Usage And Synthesis
Chemical Properties
slightly yellow crystalline powder
Uses
Aluminum tert-butoxide is utilized as a reagent in the Oppenauer oxidation of alcohols to ketones. It is also used in Meerwein-Ponndorf-Verley reduction of ketones. It is actively involved in the preparation of 1,1,2-triethoxyethene by reacting with 1,1,2,2-tetraethoxyethane followed by the elimination of alcohol.
Uses
Reagent for oxidation of alcohols to ketones; in dealcoholation of orthoesters.
Purification Methods
Crystallise it from *C6H6 and it sublimes it at 180o. [McElvain & Davie J Am Chem Soc 73 1400 1951, Beilstein 1 IV 1612.]
ALUMINUM TERT-BUTOXIDESupplier
J & K SCIENTIFIC LTD.
- Tel
- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 4006608290; 18621169109
- market03@meryer.com
INTATRADE GmbH
- Tel
- +49 3493/605464
- sales@intatrade.de
Alfa Aesar
- Tel
- 400-6106006
- saleschina@alfa-asia.com
TCI (Shanghai) Development Co., Ltd.
- Tel
- 021-67121386
- Sales-CN@TCIchemicals.com
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ALUMINUM TERT-BUTOXIDE(556-91-2)Related Product Information
- tert-Butylhydroquinone
- Potassium tert-butoxide
- Tetraethyl orthosilicate
- tert-Butyllithium
- Aluminum chloride
- p-Toluenesulfonic acid
- Aluminum Stearate
- Sodium tert-butoxide
- Aluminium isopropoxide
- Triethylaluminum
- Butylate
- tert-Butanol
- ALUMINUM TERT-BUTOXIDE
- Lithium tri-tert-butoxyaluminum hydride
- LITHIUM TRIS[(3-ETHYL-3-PENTYL)OXY]ALUMINOHYDRIDE
- LITHIUM TRI-TERT-BUTOXYALUMINODEUTERIDE
- LITHIUM TETRA(PERFLUORO-T-BUTOXY)ALUMINATE
- Lithium hydridotris(tert-butoxy)aluminate, nominally 1M in THF, packaged under Argon in resealable ChemSeal^t bottles