RUTHENIUM(III) CHLORIDE TRIHYDRATE Chemical Properties

storage temp. 

Inert atmosphere,Room Temperature

form 

Solid

color 

Blackish powder

InChI

InChI=1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChIKey

ZTWIEIFKPFJRLV-UHFFFAOYSA-K

SMILES

[Ru](Cl)(Cl)Cl.O

Safety Information

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

26-27-36/37/39

RIDADR 

UN 3260

WGK Germany 

3

HazardClass 

8

PackingGroup 

Ⅱ

Storage Class

8A - Combustible corrosive hazardous materials

Hazard Classifications

Skin Corr. 1B

RUTHENIUM(III) CHLORIDE TRIHYDRATE Usage And Synthesis

Uses

Ruthenium(III) chloride trihydrate (cas# 13815-94-6) is a commonly used catalyst for oxidation reactions.

Uses

Lewis acid; catalyst for alkyne functionalization and oxidation.

reaction suitability

core: ruthenium
reaction type: C-H Activation
reagent type: catalyst

Synthesis

N,N-dimethyl-formamide and acetone were mixed in a dry reaction flask, bipyridine and ruthenium chloride trihydrate were added to the above reaction system (molar ratio 2:1), and the resulting reaction mixture was heated to reflux and kept at reflux with stirring for about 1.5 h. After completion of the reaction, it was cooled down (ice bath) and the insoluble precipitate was collected by filtration and washed with water. The insoluble precipitate in the system was collected by filtration and washed with water, and the target metal ruthenium complex was purified by recrystallization.

RUTHENIUM(III) CHLORIDE TRIHYDRATE(13815-94-6)Related Product Information

• NIOBIUM SHEET 1.0 X 100 X 200 MM
• PRASEODYMIUM
• GADOLINIUM
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• Platinum(II)-ammonium chloride
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• Ruthenium(III) chloride
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• Hexacarbonyldi(chloro)dichlorodiruthenium(II)
• POTASSIUM PENTACHLORONITROSYLRUTHENATE(II)
• Potassium pentachlororuthenate (III) hydrate
• RUTHENIUM(III) NITROSYLCHLORIDE
• POTASSIUM MU-OXOBIS[PENTACHLORORUTHENATE(IV)] HYDRATE
• Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
• RUTHENIUM(III) CHLORIDE TRIHYDRATE
• Dimethylammonium dichlorotri(μ-chloro)bis[(R)-(+)-5,5μ-bis[di(3,5-xylyl)phosphino]-4,4μ-bi-1,3-benzodioxole]diruthenate(II)
• SODIUM DECACHLOROOXODIRUTHENATE (IV)
• Ruthenium Trichloride Trihydrate