tert-Butyl peroxyacetate Chemical Properties

Melting point:

-20 °C

Boiling point:

184.08°C (rough estimate)

Density 

0.828 g/mL at 25 °C

vapor pressure 

1.966Pa at 25℃

refractive index 

n20/D 1.412

Flash point:

99 °F

storage temp. 

Refrigerator (+4°C) + Flammables area

form 

Solution

color 

Clear

Water Solubility 

3.878g/L at 25℃

LogP

1.6 at 25℃

CAS DataBase Reference

107-71-1(CAS DataBase Reference)

EPA Substance Registry System

tert-Butyl peroxyacetate (107-71-1)

Safety Information

Hazard Codes 

F,T,O,Xi

Risk Statements 

23/24/25-36/37/38-40-65-22-10-7-45-46

Safety Statements 

16-26-36/37/39-45-62-47-14-7-53-3/7-36/37-35

RIDADR 

UN 3103 5.2

WGK Germany 

2

RTECS 

SD8925000

HazardClass 

5.2

PackingGroup 

II

HS Code 

29159000

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS

tert-Butyl peroxyacetate Usage And Synthesis

Chemical Properties

clear solution

Uses

It is used to initiate polymerization, and inorganic syntheses.

Uses

Allows the direct copper catalyzed acetoxylation of β-lactams at the 4-position.

Uses

Polymerization initiator for vinyl monomers, manufacture of polyethylene and polystyrene.

General Description

tert-Butyl peroxyacetate is sensitive to heat. Storage of tert-Butyl peroxyacetate must be done so with stringent temperature control measures. It's explosion hazard is also mitigated by mixing the peroxide with an inert solid.

Reactivity Profile

tert-Butyl peroxyacetate explodes with great violence when rapidly heated to a critical temperature; pure form is shock sensitive and detonable [Bretherick 1979 p. 602]. Upon contact with organic matter, t-butyl peroxyacetate can ignite or give rise to an explosion [Haz. Chem. Data 1973 p. 77].

Hazard

Flammable, dangerous fire risk. Oxidizer.

Health Hazard

Mild skin and eye irritant. Its toxicity is low,both via inhalation and ingestion routes.
LD₅₀ value, oral (rats): 675 mg/kg.

Fire Hazard

The pure compound is highly reactive and oxidizing, and sensitive to heat and shock.
A 75% solution in benzene or mineral spirits is the maximum assay that is sold commercially. Its benzene solution at this concentration is reactive, oxidizing, and flammable. The flash point varies depending on the solvent; the autoignition temperature not reported; the self-accelerating decomposition temperature is 93°C (199.4°F).
t-Butyl peroxyacetate forms an explosive mixture with air, explosive range not reported. It can ignite or explode when in contact with combustible organic compounds. Fire-extinguishing agent: water from a sprinkler from an explosion-resistant location; keep the containers cool.

Flammability and Explosibility

Flammable

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation. Moderate skin and eye irritant. A shockand heat-sensitive explosive. Dangerous fire hazard when exposed to heat, flame, reducing agents. To fight fire, use dry chemical, alcohol foam, spray and mist. When heated to decomposition it emits acrid smoke and fumes. See also PEROXIDES, ORGANIC; and ESTERS

storage

Store in a cool and well-ventilated placeisolated from other chemicals; protect fromphysical damage. It is shipped in glass andearthenware containers not exceeding 7 lb,inside a wooden or fiberboard box.

Purification Methods

Wash the ester with NaHCO3 from a *benzene solution, then redistil to remove *benzene [Kochi J Am Chem Soc 84 774 1962]. Handle with adequate protection due to possible EXPLOSIVE nature. [Beilstein 2 IV 391.]

tert-Butyl peroxyacetate(107-71-1)Related Product Information

• Diisobutyryl peroxide
• tert-Amyl perpivalate
• tert-Butyl peroxyneodecanoate
• tert-Butyl peroxy-3,5,5-trimethylhexanoate
• tert-Butyl peroxybenzoate
• tert-Butyl peroxy-2-ethylhexanoate
• tert-Butyl peroxyisobutyrate
• tert-Butyl peroxyacetate
• tert-Amyl peroxy-2-ethylhexanoate
• di-tert-butyl diperoxyphthalate
• tert-Amyl peroxy neodecanoate(in solution,content≤77%)
• tert-Butyl peroxypivalate
• TERT-AMYL PEROXYBENZOATE
• PERKADOX PF-DBM25
• Peroxyacetic acid
• TERT-BUTYL PERPHTHALIC ACID
• tert-butyl isononaneperoxoate
• AKOS 91883