(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Chemical Properties

Melting point:

99-104 °C

Boiling point:

402.3±38.0 °C(Predicted)

Density 

1.08

refractive index 

-199 ° (C=1.5, Acetone)

storage temp. 

-20°C

solubility 

Acetone (Slightly), Chloroform (Slightly)

form 

Solution

color 

Yellow to brown or gray

optical activity

[α]20/D 195°, c = 2 in acetone

BRN 

3207468

Safety Information

Safety Statements 

22-24/25

WGK Germany 

3

HS Code 

29309090

MSDS

• Language:English Provider:SigmaAldrich

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE Usage And Synthesis

Chemical Properties

White crystalline powder

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-Toluenesulfinate is a reactant used in the synthesis of sulfoxide pincer complexes of Mg, Rh and Ir.

Uses

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate can react with:

• metal ketimines to form enantiopure sulfinimines
• p-(methylthio)benzaldehyde to form (S)-(-)-N-(4-methylthiobenzylidene)-p-toluenesulfinimine

General Description

(1R,2S,5R)-(-)-Menthyl (S)-p-toluenesulfinate is mainly used for the introduction of p-toluenesulfinyl group in asymmetric synthesis.

(1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE(1517-82-4)Related Product Information

• p-Toluenesulfonic acid
• P-TOLUENESULFINIC ACID
• (1S,2R,5S)-MENTHYL (R)-P-TOLUENESULFINATE,(1S,2R,5S)-(+)-MENTHYL (R)-P-TOLUENESULFINATE,(+)-(1S)-Menthyl (R)-p-toluenesulfinate
• DL-Menthol
• 2,5-DIMETHYLCYCLOHEXANOL
• 3,7-DIMETHYL-1-OCTANOL
• METHYL P-TOLUENESULFINATE
• (1R,2S,5R)-(-)-MENTHYL (S)-P-TOLUENESULFINATE
• 2-Methylcyclohexanol
• (+)-MENTHOL
• DL-Menthol
• 2-ETHYLCYCLOHEXANOL