ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Basic information
- Product Name:
- (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
- Synonyms:
-
- (S)-(-)-2-[(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
- (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-ISOPROPYL)-4,5-DIHYDROOXAZOLE
- (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(1-METHYLETHYL)-4,5-DIHYDROOXAZOLE
- (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4,5-DIHYDRO-4-ISOPROPYLOXAZOLE
- (S)-(-)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYL-2-OXAZOLINE
- (-)(4S)-2-[2-(DIPHENYLPHOSPHINO)PHENYL]-4-(2-PROPYL)OXAZOLINE
- (4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE
- (S)-(-)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-
- CAS:
- 148461-14-7
- MF:
- C24H24NOP
- MW:
- 373.43
- Product Categories:
-
- Chiral Phosphine
- PHOX Series
- organophosphine ligand
- Mol File:
- 148461-14-7.mol
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Chemical Properties
- Melting point:
- 85-90 °C
- alpha
- -44° (c 1.4, CHCl3)
- Boiling point:
- 492.7±28.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 4.31±0.70(Predicted)
- form
- Powder
- color
- white
- optical activity
- [α]20/D 48±3°, c = 1% in chloroform
- Sensitive
- air sensitive
- BRN
- 5879302
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Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 37/39-26-24/25
- WGK Germany
- 3
- F
- 10-23
- Hazard Note
- Irritant
- HS Code
- 29349990
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
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(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLE Usage And Synthesis
Chemical Properties
White crystalline powder
Reactions
- Chiral ligand used in the asymmetric reduction of highly substituted olefins.
- Chiral ligand used in the enantioselective Heck reaction. The success of the reaction is due to the fact that the catalytic system does not promote double bond isomerization.
- Chiral ligand used in the entantioselective palladium-catalyzed allylic substitution of sodium benzotriazole.
- Decarboxylative allylic alkylation.
(4S)-(-)-4,5-DIHYDRO-2-[2'-(DIPHENYLPHOSPHINO)PHENYL]-4-ISOPROPYLOXAZOLESupplier
J & K SCIENTIFIC LTD.
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Energy Chemical
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Adamas Reagent, Ltd.
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Daicel Chiral Technologies (China)CO.,LTD
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- 021-50460086-9 15921403865
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