Basic information Safety Supplier Related

Bis(hexylene glycolato)diboron

Basic information Safety Supplier Related

Bis(hexylene glycolato)diboron Basic information

Product Name:
Bis(hexylene glycolato)diboron
Synonyms:
  • 4,4,6-TRIMETHYL-2-(4,4,6-TRIMETHYL-1,3,2-DIOXABORINAN-2-YL)-1,3,2-DIOXABORINANE
  • 4,4,4',4',6,6'-HEXAMETHYL-2,2'-BI-1,3,2-DIOXABORINANE
  • BIS(2-METHYL-2,4-PENTANEDIOLATO)DIBORON
  • BIS(1,3,3-TRIMETHYL-1,3-PROPANEDIOLATO)DIBORON
  • BIS(HEXYLENE GLYCOLATO)DIBORON
  • 4,4,4',4',5,5'-Hexamethyl-2,2'-bi(1,3,2-dioxaborolane)
  • Bis(1,3,3-trimethyl-1,3-propanediolato)diboron Bis(2-methyl-2,4-pentanediolato)diboron 4,4,4',4',6,6'-Hexamethyl-2,2'-bi-1,3,2-dioxaborinane
  • Bis(hexyleneglycolato)diboron,99%
CAS:
230299-21-5
MF:
C12H24B2O4
MW:
253.94
Product Categories:
  • B (Classes of Boron Compounds)
  • Diboron Esters
  • CHIRAL CHEMICALS
  • Borylation Reagents
  • Boronic Acids and Derivatives
  • Organometallic Reagents
  • DIBORON SERIES
  • Organoborons
Mol File:
230299-21-5.mol
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Bis(hexylene glycolato)diboron Chemical Properties

Melting point:
98-102 °C (lit.)
Boiling point:
242.8±7.0 °C(Predicted)
Density 
0.97±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
white
Water Solubility 
Insoluble
CAS DataBase Reference
230299-21-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29349990

MSDS

  • Language:English Provider:ACROS
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Bis(hexylene glycolato)diboron Usage And Synthesis

Chemical Properties

White crystalline powde

Uses

suzuki reaction

Uses

Bis(hexylene glycolato)diboron can be used as a reagent:

  • To prepare aryl boronate esters via metal-catalyzed direct C-H borylation of aryl compounds.
  • In the chemoselective synthesis of C?C coupling products via nickel catalyzed coupling of primary and secondary alkyl halides.
  • In the nickel-catalyzed regioselective arylboration of terminal nonactivated alkenes to yield alkyl boranes.

Bis(hexylene glycolato)diboronSupplier

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