(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Basic information
- Product Name:
- (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
- Synonyms:
-
- (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP
- 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aR)- (9CI)
- (R)-diMethylene-[7,7′-(1,1′-spiroindan)]-phenylphospholane
- (11aR)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1',7'-ef]phosphocin
- (R)-SITCP
- (R)-dimethylene-\n[7,7′-(1,1′-spiroin\ndan)]-phenylphos\npholane
- (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd
- 17ef]phosphocin, min. 97% (R)-SITCP
- CAS:
- 856407-37-9
- MF:
- C25H23P
- MW:
- 354.42
- Product Categories:
-
- Chiral Phosphine
- Chiral Spiro Ligand
- Mol File:
- 856407-37-9.mol
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(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Chemical Properties
- Melting point:
- 148-149°C
- alpha
- +6° (c 0.5, CH2Cl2)
- Boiling point:
- 505.6±50.0 °C(Predicted)
- storage temp.
- -20°C, protect from light, stored under nitrogen
- form
- solid
- color
- white
- Sensitive
- air sensitive
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(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP Usage And Synthesis
Reaction
- Phosphine-catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
- Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylative [4+2] cyclization.
- Catalytic, enantioselective carbon-oxygen bond formation – phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
- Use of a new spirophosphine to achieve catalytic, enantioselective [4+1] annulations of amines with allenes to generate dihydropyrroles.
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCPSupplier
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(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:17ef]phosphocin, min. 97% (R)-SITCP(856407-37-9)Related Product Information
- (R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine
- Phenyl-[(S)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy
- (R)-(+)-7,7'-BIS[DI(4-METHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
- (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX
- 4H-Diindeno[7,1-cd:1',7'-ef]phosphocin,5,6,10,11,12,13-hexahydro-5-phenyl-, (11aS)- (9CI)